c full N2/O2/H2O/CO2 model; March 1994
c
symbol energy yinit MolWt StatWt
Csubv ion_Z Q_flag
e 0.00 0. 0 1. 1.5 -1 F
N2 0.00 0.79 28 1. 2.5 0 T
N2v 0.29 0. 28 1. 2.5 0 F
N2A 6.17 0.0 28 1. 2.5 0 T
N2a 8.40 0.0 28 1. 2.5 0 T
N2+ 15.60 0.0 28 1. 2.5 +1
F
N4+ 15.60 0.0 56 1. 2.5 +1 F
O2 0.00 0.21 32 1. 2.5 0 T
O2v 0.00 0.0 32 1. 2.5 0 F
O2a1D 0.98
0.0 32 1. 2.5 0 T
O2B1S 1.63
0.0 32 1. 2.5 0 T
O2+ 12.06 0.0 32 1. 2.5 +1 F
O4+ 12.06 0.0 64 1. 2.5 +1 F
O2- -0.43 0.0 32 1. 2.5 -1 F
O 5.15 0.0 16 1. 1.5 0 T
O1D 7.30 0.0 16 1. 1.5 0 F
O1S 9.10 0.0 16 1. 1.5 0 F
O+ 13.66 0.0 16 1. 1.5 +1 F
O- 3.70 0.0 16 1. 1.5 -1 F
O3 1.51 0.0 48 1. 2.5 0 T
O3- -0.60 0.0 48 1. 2.5 -1 F
O3+ 14.31 0.0 48 1. 2.5 +1 F
O4- 0. 0.0 64 1. 2.5 -1 F
N 9.75 0.0 14 1. 1.5 0 F
NO 0.93 0.0 30 1. 2.5 0 F
NO+ 9.28 0.0 30 1. 2.5 +1 F
NO- 0.91 0.0 30 1. 2.5 -1 F
NO2 0.37 0.0 46
1. 2.5 0
F
NO2- -2.10
0.0 46 1. 2.5 -1 F
NO3 0.74 0.0 62 1. 2.5 0 F
NO3- -2.00
0.0 62 1. 2.5 -1 F
N2O 0.88 0.0 44 1. 2.5 0
T
N2O3 0.86
0.0 76 1. 2.5 0 F
H2O -2.51 0.025 18 1. 2.5 0 T
H 4.48 0.0 1 1.
1.5 0 F
H- 1.49 0.0 1 1. 1.5 -1 F
OH 5.12 0.0 17 1. 2.5 0 F
OH- -1.43 0.0 17 1. 2.5 -1 F
H2 0.00 0.0 2 1. 2.5 0
F
H2O+ 12.62
0.0 18 1. 2.5 +1 F
H3O+ 4.80
0.0 19 1. 2.5 +1 F
OH+ 12.94 0.0 17 1. 2.5 +1 F
HO2 0.217 0.0 33 1. 2.5 0 F
H2O2 -1.41
0.0 34 1. 2.5 0 F
H2O2- 2.9
0.0 34 1. 2.5 -1 F
H2O3- -1.23
0.0 50 1.
2.5 -1 F
H2O4- -1.4
0.0 66 1. 2.5 -1 F
H3O2- -2.50
0.0 35 1. 2.5 -1 F
NO-w 0.28
0.0 48 1. 2.5 -1 F
NO2-w -2.76
0.0 64 1. 2.5 -1 F
NH 0.00 0.0 15 1. 2.5 0 F
NH2 0.00 0.0 16 1. 2.5 0 F
HNO -0.50 0.0 31 1. 2.5 0 F
HNO2 -0.79
0.0 47 1. 2.5 0 F
HNO3 -1.40
0.0 63 1. 2.5 0 F
CO2 -4.06 0.00 44 1.0
3.5 0 T
CO2v -3.977 0. 44 1.0
3.5 0 F
CO -1.18 0. 28 1.0
2.5 0 F
CO3- 0. 0. 60 1.0
2.5 -1 F
CO4- 0. 0. 76 1.0
2.5 -1 F
CN 0. 0. 26 1.0
2.5 0 F
HCO 0. 0. 29 1.0
2.5 0 F
Ar 0.0 0.0 40 1.0
1.5 0 T
End_List
/
c Begining of Air Chemistry:
c Electron Processes:
c Processes involving solution of
Boltzmann's eqn:
Boltz
/
1 N2
+ 1 e -> 1
N2A + 1 e /
N2
N2A /
Boltz
/
1 N2
+ 1 e -> 1
N2a + 1 e /
N2
N2a /
Boltz
/
1 N2
+ 1 e -> 1
N2+ + 2 e /
N2
N2+ /
Boltz /
1 O2
+ 1 e -> 1
O2+ + 2 e /
O2
O2+ /
Boltz /
1 O2
+ 1 e -> 1 O2a1D
+ 1 e /
O2
O2a1D /
Boltz /
1 O2
+ 1 e -> 1 O2B1S
+ 1 e /
O2
O2B1S /
Boltz
/
1 O2
+ 1 e -> 1 O + 1 O + 1 e /
O2
O+O /
Boltz
/
1 O2
+ 1 e -> 1
O- + 1 O /
O2
O+O- /
Boltz
/
1 O2
+ 1 e -> 1
O2- /
O2
O2- /
Boltz
/
1 O
+ 1 e -> 1
O+ + 2 e /
O
O+ /
Boltz
/
1 O
+ 1 e -> 1
O1D + 1 e /
O
O1D /
Boltz
/
1 O
+ 1 e -> 1
O1S + 1 e /
O
O1S /
Boltz /
1 N2a
+ 1 e -> 1
N2+ + 2 e /
N2a
N2+ /
Boltz /
1 N2A
+ 1 e -> 1
N2+ + 2 e /
N2A
N2+ /
Boltz /
1 O2a1D + 1 e -> 1 O
+ 1 O + 1 e /
O2a1D
O+O /
Boltz
/
1 O2a1D + 1 e -> 1 O2+
+ 2 e /
O2a1D
O2+ /
Boltz
/
1 O2B1S + 1 e -> 1 O + 1 O
+ 1 e /
O2B1S
O+O /
Boltz
/
1 O2B1S + 1 e -> 1 O2+
+ 2 e /
O2B1S
O2+ /
Boltz
/
1 N2O
+ 1 e -> 1
N2 + 1 O- /
N2O
N2+O- /
Boltz
/
1 O3
+ 1 e -> 1
O3+ + 2 e /
O3
O3+
/
Boltz
/
1 H2O
+ 1 e -> 1 H + 1 OH
+ 1 e /
H2O
H+OH /
Boltz
/
1 H2O
+ 1 e -> 1
O1D + 1 H2 + 1 e /
H2O
O*+H2 /
Boltz /
1 H2O
+ 1 e -> 1
H2O+ + 2 e /
H2O
H2O+ /
Boltz
/
1 H2O
+ 1 e -> 1
OH- + 1 H /
H2O
OH-+H /
Boltz
/
1 H2O
+ 1 e -> 1
H- + 1 OH /
H2O
H-+OH /
Boltz
/
1 H2O
+ 1 e -> 1
H2 + 1 O- /
H2O
H2+O- /
c
**********************************************************************
c Electron "temperature"
dependent processes: /
c Recombination:
Etemp
/
1 e
+ 1 N2+ -> 1 N + 1 N /
5.400e-08
-0.39 / 2.2e-7 @
300K Biondi (76)
Etemp
1 e
+ 1 N2+ + 1 O2 -> 1 N2 + 1 O2
/
1.000e-26 /
Etemp
/
1 e
+ 1 O2+ -> 1 O + 1 O /
2.700e-08
-0.56 / 2.1e-7 @
300K Biondi (76)
Etemp
/
1 e
+ 1 O2+ -> 1 O + 1 O1D /
1.950e-07 /
Etemp
1 e
+ 1 O2+ + 1 O2 -> 1 O2 + 1 O2
/
8.000e-29 /
Etemp /
1 e
+ 1 NO+ -> 1 N + 1 O /
6.600e-08
-0.5 / 4.1e-7 @
300K Biondi (76)
Etemp
/
1 e
+ 1 NO+ + 1 O2 -> 1 NO + 1 O2
/
3.100e-23
-1.5 /
Etemp
/
1 e
+ 1 N4+ -> 1
N2 + 1 N + 1 N /
2.000e-06 /
Etemp
/
1 e
+ 1 O4+ -> 1
O2 + 1 O + 1 O /
2.000e-06 /
Etemp
/
1 e
+ 1 O4+ -> 1
O2 + 1 O2 /
1.100e-07 /
Etemp
/
1 e
+ 1 O+ + 1 e -> 1 O + 1 e
/
8.750e-27
-4.5 / CRR
Etemp
/
1 e
+ 1 O+ + 1 N2 -> 1 O + 1 N2
/
5.600e-27
-4.5 / CRR
Etemp /
1 e
+ 1 O+ + 1 O2 -> 1 O + 1 O2
/
5.600e-27
-4.5 / CRR
Etemp
/
1 e
+ 1 H2O+ -> 1 H +
1 OH /
1.100e-06
-0.5 / 6.6e-6 @ 300K
Etemp
/
1 e
+ 1 H2O+ -> 1 O + 1 H2 /
3.800e-07
-0.5 / 2.4e-6 @ 300K
Etemp
/
1 e
+ 1 H2O+ -> 1 O + 1 H
+ 1 H /
4.800e-07
-0.5 / 3.0e-6 @ 300K
Etemp /
1 e
+ 1 H3O+ -> 1
H2O + 1 H /
2.200e-06
-0.08 / 3.0e-6 @
300K Biondi (82) value for H3O+*(H2O)2
c Attachment:
Etemp /
1 e
+ 1 O2 + 1 O2 -> 1 O2- + 1 O2
/
2.200e-30 /
Etemp
1 e
+ 1 O2 + 1 N2 -> 1 O2- + 1 N2 /
1.000e-31 / K92 (#48)
Etemp
1 e
+ 1 O + 1 O2 -> 1 O- + 1 O2
/
1.000e-31 /
Etemp
1 e + 1 O + 1 N2
-> 1 O- + 1 N2 /
1.000e-31 /
c Etemp
c 1 e
+ 1 HO2 -> 1 H + 1 O2- /
c
5.000e-09 /
Etemp
1 e
+ 1 NO2 -> 1
O- + 1 NO /
3.400e-10
-2.4 3. / McDaniel, V. IV, p. 1472-1473
Etemp
1 e
+ 1 NO2 -> 1
NO2- /
4.000e-11 / McDaniel, V. IV, p. 1472-1473
Etemp
1 e
+ 1 O3 -> 1
O- + 1 O2 /
1.000e-11 /
c Etemp
c 1 e
+ 1 O -> 1
O- /
c
1.300e-15 /
Etemp
1 e
+ 1 O3 + 1 O2 -> 1 O3- + 1 O2
/
4.600e-28 /
Etemp
1 e
+ 1 NO -> 1
O- + 1 N /
3.400e-06
-8.2 15.2 / McDaniel, V. IV, p. 1472-1473
Etemp
1 e
+ 1 NO + 1 N2 -> 1 NO- + 1 N2 /
4.000e-29 / Smirnov, p. 117; k=4x10^-11 for [N2]=10^18
Etemp
1 e
+ 1 HNO2 -> 1
NO2- + 1 H /
5.000e-08 / McDaniel, V. IV, p. 1472-1473
Etemp
1 e
+ 1 HNO3 -> 1
NO2- + 1 OH /
5.000e-08 / McDaniel, V. IV, p. 1472-1473
c Etemp
c 1 e
+ 1 N2O + 1 N2 -> 1 N2O- + 1 N2
/
c 0.030e-31 / Smirnov, p. 117
c Dissociation:
Etemp
1 e
+ 1 O3 -> 1
O2 + 1 O + 1 e /
2.240e-08 /
c **********************************************************************
c Atomic & Molecular Reactions: Neutral Chemistry
Chem
1 O
+ 1 O + 1 N2 -> 1 O2 + 1 N2
/
6.498e-35
0. -1039. / NIST fit 196-5000 K
c K92 (#91): 2.76e-34 0. -720.
Chem
1 O
+ 1 O + 1 N -> 1 O2 + 1 N
/
6.498e-35
0. -1039. / use the rate for M = N2
Chem
1 O
+ 1 O2 + 1 O2 -> 1 O3 + 1 O2 /
2.413e-34
-1.029 -238.9 / NIST fit 80-3000 K; K92 (#95) has
c
6.9e-34 -1.25 0.0
Chem
1 O
+ 1 O2 + 1 N2 -> 1 O3 + 1 N2
/
2.413e-34
-1.029 -238.9 / NIST fit 80-3000 K; K92 (#94) has
c
6.2e-34 -2.0 0.0
Chem
1 O
+ 1 O2 + 1 O3 -> 1 O3 + 1 O3
/
1.430e-33
-2.
/ SGG87
Chem
1 O
+ 1 O2 + 1 O -> 1 O3 + 1 O
/
2.150e-34
0. -345. / SGG87
Chem
1 O
+ 1 O3 -> 2
O2 /
1.529e-11
0. 2185. / NIST fit 197-2000 K
c K92 (#82):
2.0e-11 0. -2300.
Chem
1 O
+ 1 NO + 1 N2 -> 1 NO2 + 1 N2
/
1.064e-31
-1.682 46.26 / NIST fit 200-3000 K; see also K92 (#96)
Chem
1 O
+ 1 NO + 1 O2 -> 1 NO2 + 1 O2
/
1.064e-31
-1.682 46.26 / NIST fit 200-3000 K; see also K92 (#96)
Chem
1 O
+ 1 NO -> 1
NO2 /
2.221e-11
0.459 -92.64 / NIST fit
200-1500 K
Chem
1 O
+ 1 NO -> 1
O2 + 1 N /
4.222e-11
0.0 23200. / NIST fit 1500-5000 K
Chem
1 O
+ 1 NO + 1 N2 -> 1 NO2 + 1 N2 /
1.064e-31
-1.682 46.26 / NIST fit 200-3000 K
Chem
1 O
+ 1 NO2 -> 1
O2 + 1 NO /
9.090e-12
0.18
/ K92 (#81)
c Chem
c 1 O
+ 1 NO2 -> 1 NO3 /
c
2.200e-11 / NIST fit; 200-400 K
Chem
1 O
+ 1 NO2 + 1 N2 -> 1 NO3 + 1 N2
/
1.065e-31
-2.157 46.59 / NIST fit; 200-400 K
Chem
1 O
+ 1 NO2 + 1 O2 -> 1 NO3 + 1 O2
/
1.065e-31
-2.157 46.59 / NIST fit 200-400 K; see K92 (#97)
Chem
1 O
+ 1 NO2 + 1 N2 -> 1 NO3 + 1 N2 /
1.065e-31
-2.157 46.59 / NIST fit 200-400 K; see K92 (#97)
Chem
1 O
+ 1 NO3 -> 1
O2 + 1 NO2 /
1.000e-11 / K92 (#83); NIST
c ---------------
Chem
1 N
+ 1 N + 1 N2 -> 1 N2 + 1 N2
/
8.270e-34
0. -500. / K92 (#90)
c NIST: ref 91PRA/SMI has k = 4.1e-34,
8.6e-34, 1.1e-33 for
c M = He, Ar, Xe respectively @ 293 K
Chem
1 N
+ 1 N + 1 N -> 1 N2 + 1 N
/
23.320e-34 0.
-500. / use rate
coefficient for M = N2
c but multiplied by 2.82 to reflect the
measurement of 1.25e-32
c by ref 88KNI/RUB listed in the NIST
database
Chem
1 N
+ 1 NO -> 1
N2 + 1 O /
3.513e-11
0. 49.84 / NIST fit 196-3000 K; see K92 (#76)
Chem
1 N
+ 1 O2 -> 1 NO + 1 O /
1.001e-11
0. 3473. / NIST fit 200-1000 K; see K92 (#74)
Chem
1 N
+ 1 NO2 -> 1
N2O + 1 O /
3.000e-12 / K92 (#79); NIST too
Chem
1 N
+ 1 O3 -> 1
NO + 1 O2 /
1.000e-16 / NIST; K92 (#75) has k <=
2.e-16
c ---------------
Chem
1 NO
+ 1 O3 -> 1 O2 + 1 NO2 /
4.300e-12
0. 1560. / K92 (#85)
c the 195-500 K fit from the NIST database
is 2.445e-12 0. 1446.
Chem
1 NO2
+ 1 O3 -> 1
NO3 + 1 O2 /
1.893e-13
0. 2542. / NIST fit 200-363 K; K92 (#87) has
Chem
1 NO3
+ 1 O3 -> 2
O2 + 1 NO2 /
1.000e-17 / NIST
c 1.2e-13
0. 2450.
c ---------------
Chem
1 NO
+ 1 NO2 + 1 N2 -> 1 N2O3 + 1 N2
/
9.110e-33 / NIST
c Chem
c 1 NO
+ 1 NO2 -> 1
N2O3 /
c
3.400e-12 / NIST
Chem
1 NO
+ 1 NO3 -> 2
NO2 /
1.113e-11
0. -220.9 / NIST fit 200-1100 K; K92 (#86) has
1.7e-11
c
------------------- Humid Air Chemistry Starts Here ---------------------
c Neutral Chemistry:
Chem
1 H
+ 1 O2 -> 1 O + 1 OH /
1.168e-10
0.2789 7860. / NIST fit 250-5300 K
Chem
1 H
+ 1 O2 + 1 H2 -> 1 HO2 + 1 H2
/
5.790e-32
-0.8 0. / NIST (84WAR) 300-2500
K
Chem
1 H
+ 1 O2 + 1 N2 -> 1 HO2 + 1 N2 /
5.940e-32
-1.0 0. / NIST (86TSA/HAM)
300-2500 K
Chem
1 H
+ 1 O2 + 1 O2 -> 1 HO2 + 1 O2
/
5.940e-32
-1.0 0. / NIST use rate coeff for M
= N2
c note that the rate coefficient for M = Ar
is lower: 2.032e-32 -0.8 0.
Chem
1 H
+ 1 OH + 1 N2 -> 1 H2O + 1 N2
/
6.880e-31
-2. 0. / NIST (86TSA/HAM)
300-3000 K
Chem
1 H + 1 OH + 1 O2
-> 1 H2O + 1 O2 /
6.880e-31
-2. 0. / use value for M
= N2
Chem
1 H
+ 1 OH + 1 H2O -> 1 H2O + 1 H2O
/
4.360e-30
-2. 0. / NIST (84WAR) 1000-3000 K
Chem
1 H
+ 1 NO2 -> 1
NO + 1 OH /
2.200e-10
0. 182. / NIST (91KO/FON) 296-760
K
Chem
1 H
+ 1 O3 -> 1
O2 + 1 OH /
7.788e-11
0.2551 327.8 / NIST fit 196-2000 K
Chem
1 H
+ 1 O3 -> 1
HO2 + 1 O /
7.500e-13 / NIST (79FIN/KLE); k <=
7.5e-13
Chem
1 H
+ 1 HO2 -> 1
H2 + 1 O2 /
2.571e-11
0.5598 346. / NIST fit 245-2500
K
Chem
1 H
+ 1 HO2 -> 1
OH + 1 OH /
2.356e-10
0. 373.7 / NIST fit 245-2500 K
Chem
1 H
+ 1 HO2 -> 1
H2O + 1 O /
9.180e-11
0. 971.9 / NIST fit 245-773 K
c Chem
c 1 H + 1 O2 ->
1 HO2 /
c
7.500e-11 / NIST (87DEM/GOL)
c Chem
c 1 H
+ 1 OH -> 1
H2O /
c
2.700e-14 / NIST (77ZEL/ERL) @
300 K; (72FRI/SUT) has 7.3e-14 @ 2130 K
Chem
1 H
+ 1 HNO -> 1
H2 + 1 NO /
4.270e-12
0. -998.1 / NIST fit 295-2100 K
Chem
1 H
+ 1 HNO -> 1 OH + 1 NH /
2.410e-9
-0.5 9010. / NIST fit 359-3000 K
Chem
1 H
+ 1 HNO -> 1 O + 1 NH2 /
1.050e-9
-0.3 14730. / NIST (91COH/WES) 550-3000
K
Chem
1 H
+ 1 NO -> 1
NH + 1 O /
9.290e-10
-0.10 35220. / NIST (91COH/WES)
1300-3000 K
Chem
1 H
+ 1 NO -> 1
OH + 1 N /
2.111e-10
0.0 24330. / NIST fit 1750-4500 K
Chem
1 H
+ 1 NO + 1 N2 -> 1 HNO + 1 N2
/
7.327e-32
-1.318 184.3 / NIST fit 231-704 K
Chem
1 H
+ 1 NO + 1 O2 -> 1 HNO + 1 O2
/
7.327e-32
-1.318 184.3 / NIST fit 231-704 K
Chem
1 H
+ 1 NO3 -> 1
NO2 + 1 OH /
1.100e-10 / NIST (88BOO/CAN)
Chem
1 H
+ 1 H2O2 -> 1
OH + 1 H2O /
4.000e-11
0. 2000. / NIST (86TSA/HAM)
300-2500 K
Chem
1 H
+ 1 H2O2 -> 1
H2 + 1 HO2 /
8.000e-11
0. 4000. / NIST (86TSA/HAM)
300-2500 K
c ---------------
Chem
1 OH
+ 1 OH -> 1
H2O + 1 O /
1.549e-13
1.408 -267.3 / NIST fit 200-2500 K
Chem
1 OH
+ 1 O -> 1
O2 + 1 H /
2.105e-11
-0.186 153.9 / NIST fit 200-5000 K
Chem
1 OH
+ 1 H -> 1 H2 + 1 O /
1.123e-14
3.406 1233. / NIST fit 298-2500 K
Chem
1 OH
+ 1 H2 -> 1
H2O + 1 H /
2.313e-12
1.47 1761. / NIST fit 200-3000 K
Chem
1 OH
+ 1 O3 -> 1
HO2 + 1 O2 /
1.472e-12
0. 932.7 / NIST fit 200-450 K
Chem
1 OH
+ 1 HO2 -> 1
H2O + 1 O2 /
4.381e-11
0. -110.9 / NIST fit 200-2550 K
Chem
1 OH
+ 1 OH + 1 N2 -> 1 H2O2 + 1 N2
/
6.050e-31
-3. 0. / NIST (86TSA/HAM) 300-2500 K; the general
fit
c is 1.543e-31
-2.021 -183.6 over 200-2500 K
Chem
1 OH
+ 1 OH + 1 O2 -> 1 H2O2 + 1 O2
/
6.050e-31
-3. 0. / NIST (86TSA/HAM) 300-2500 K; same as M =
N2
Chem
1 OH
+ 1 OH + 1 H2O -> 1 H2O2 + 1 H2O
/
1.543e-31
-2.021 -183.6 / use general fit from NIST;
c NIST ref
88ZEL/EWI have 4.e-30 at 300 K
Chem
1 OH
+ 1 H2O2 -> 1
H2O + 1 HO2 /
4.529e-12
0. 288.9 / NIST fit 200-2500 K
Chem
1 OH
+ 1 HNO2 -> 1
H2O + 1 NO2 /
1.800e-11
0. 390. / NIST (89ATK/BAU)
280-430 K
Chem
1 OH + 1 N2O -> 1 HO2 + 1 N2 /
3.696e-13
0. 2740. / NIST fit 298-2700 K
c Chem
c 1 OH
+ 1 OH -> 1
H2O2 /
c
1.510e-11 -0.37 0. /
NIST (87BRO/COB) 200-1500 K
Chem
1 OH
+ 1 NO + 1 N2 -> 1 HNO2 + 1 N2
/
3.924e-32
0. -794.2 / NIST fit 200-505 K
Chem
1 OH
+ 1 NO + 1 O2 -> 1 HNO2 + 1 O2
/
3.924e-32
0. -794.2 / NIST fit 200-505 K
Chem
1 OH
+ 1 NO2 -> 1
HO2 + 1 NO /
3.300e-11
0. 3360. / NIST (80HOW) 452-1115 K
Chem
1 OH
+ 1 NO2 + 1 N2 -> 1 HNO3 + 1 N2
/
8.378e-30
-3.878 409.3 / NIST fit 200-1200 K
Chem
1 OH
+ 1 NO2 + 1 O2 -> 1 HNO3 + 1 O2
/
8.378e-30
-3.878 409.3 / NIST fit 200-1200 K
Chem
1 OH
+ 1 NO3 -> 1
HO2 + 1 NO2 /
2.300e-11 / NIST (89ATK/BAU)
Chem
1 OH
+ 1 HNO -> 1 H2O + 1 NO /
1.266e-11
0.9904 334.2 / NIST fit 298-4000 K
Chem
1 OH
+ 1 HNO3 -> 1
H2O + 1 NO3 /
4.006e-14
0. -317.6 / NIST fit 200-1100 K
c ---------------
Chem
1 HO2
+ 1 O3 -> 1
OH + 2 O2 /
1.752e-15
0. -628.3 / NIST fit 200-413 K
Chem
1 HO2
+ 1 HO2 -> 1
H2O2 + 1 O2 /
3.000e-12 / NIST (86TSA/HAM) 300-2500 K
Chem
1 HO2
+ 1 O -> 1
OH + 1 O2 /
2.900e-11
0. -200. / NIST (86TSA/HAM) 300-2500 K
Chem
1 HO2
+ 1 NO -> 1
OH + 1 NO2 /
3.600e-12
0. -240. / NIST (89ATK/BAU) 230-500
K
c & (84HAN/SAL) 1000-2000 K
Chem
2 HO2
+ 1 N2 -> 1
H2O2 + 1 O2 + 1 N2 /
1.900e-33
0. -980. / NIST (89ATK/BAU) 230-420
K
Chem
1 HO2
+ 1 HO2 + 1 O2 -> 1 H2O2 + 2 O2
/
1.900e-33
0. -980. / use rate coeff for M =
N2
Chem
1 HO2
+ 1 NO -> 1
O2 + 1 HNO /
9.100e-19
0. -2819. / NIST (79HOW) 271-303 K
Chem
1 HO2
+ 1 NO -> 1
OH + 1 NO2 /
3.500e-12
0. -240. / NIST (89ATK/BAU)
230-2000 K
Chem
1 HO2
+ 1 NO2 -> 1
HNO2 + 1 O2 /
1.200e-13 / NIST (75COX)
c Chem
c 1 HO2
+ 1 NO -> 1
HNO3 /
c
1.400e-13 / NIST (75COX/DER)
Chem
1 HO2
+ 1 N -> 1 OH + 1 NO
/
2.200e-11 / NIST (83BRU/SCH2); 1 entry
Chem
1 HO2
+ 1 NO3 -> 1
HNO3 + 1 O2 /
9.210e-13 / NIST; for O2 + prod on RHS, k=4.3e-12 (89ATK/BAU)
c ---------------
Chem
1 N
+ 1 OH -> 1
NO + 1 H /
3.917e-11
0. -72.36 / NIST fit 250-515 K
Chem
1 N
+ 1 OH -> 1 O + 1 NH /
1.880e-11
0.1 10700. / NIST (91COH/WES) 500-3000
K
Chem
1 O
+ 1 H2 -> 1
OH + 1 H /
1.501e-13
2.844 2834. / NIST fit 293-3532 K
Chem
1 O
+ 1 H2O2 -> 1
OH + 1 HO2 /
1.792e-13
2.919 1394. / NIST fit 200-2500 K
Chem
1 N2O3
+ 1 H2O -> 2
HNO2 /
6.300e-11
0. 4468. / NIST (75ENG/COR) 298-323
K
Chem
1 HNO2
+ 1 O -> 1
OH + 1 NO2 /
1.000e-15 / NIST (78KAI/JAP2) k <=
1.e-15
Chem
1 HNO3
+ 1 O -> 1
OH + 1 NO3 /
3.000e-17 / NIST; k<= 3.e-17
Chem
1 HNO2
+ 1 NO3 -> 1
HNO3 + 1 NO2 /
2.000e-15 / NIST (1 entry); k<=
2.e-15
Chem
1 H2O2
+ 1 NO3 -> 1
HO2 + 1 HNO3 /
2.000e-15 / NIST (1 entry); k<=
2.e-15
c Excited State Chemistry:
Chem
1 N2A
+ 1 H2O -> 1
H2 + 1 N + 1 NO /
1.000e-10 /
Chem
1 N2a
+ 1 H2O -> 1
H2 + 1 N + 1 NO /
1.000e-10 /
c ---------------
Chem
1 O1D
+ 1 H2O -> 1
OH + 1 OH /
2.000e-10 / A89
Chem
1 O1D
+ 1 H2 -> 1
OH + 1 H /
1.000e-10 / NIST; no T dependence 200-350 K
Chem
1 O1D
+ 1 H2O -> 1
H2 + 1 O2 /
2.300e-10 / NIST
Chem
1 O1D
+ 1 H2O2 -> 1
H2O + 1 O2 /
5.200e-10 / NIST (76FLE/HUS)
c ---------------
Chem
1 O1S
+ 1 H2O -> 1 O + 1 H2O /
3.000e-10 / S&B78
Chem
1 O1S
+ 1 H2O -> 1
OH + 1 OH /
5.000e-10 / S&B78
Chem
1 O1S
+ 1 H2O -> 1
H2 + 1 O2 /
5.000e-10 / S&B78
c ---------------
Chem
1 O2a1D + 1 H2O -> 1 O2 + 1 H2O /
5.000e-18 /
Chem
1 O2B1S + 1 H2O -> 1 O2 + 1 H2O /
4.000e-12 /
c Ion - Molecule:
c Positive Ion
Chem
1 O+
+ 1 H2 -> 1
OH+ + 1 H /
1.000e-10 / A93
Chem
1 O+
+ 1 H2O -> 1
H2O+ + 1 O /
2.600e-09 / A93
Chem
1 O2+
+ 2 H2O -> 1
H3O+ + 1 OH + 1 O2 /
2.000e-28 /
Chem
1 O4+
+ 2 H2O -> 1
H3O+ + 1 OH + 2 O2 /
2.000e-28 /
Chem
1 N2+
+ 1 H2O -> 1
H2O+ + 1 N2 /
2.200e-09 / A93
Chem
1 H2O+
+ 1 O2 -> 1
H2O + 1 O2+ /
3.300e-10 / A93
Chem
1 H2O+
+ 1 H2O -> 1 H3O+ + 1 OH
/
1.850e-09 / A93
Chem
1 OH+
+ 1 O2 -> 1
OH + 1 O2+ /
3.800e-10 / A93
Chem
1 NO+
+ 2 H2O -> 1
H3O+ + 1 HNO2 /
2.000e-28 /
c Negative Ion
Chem
1 O-
+ 1 H2 -> 1
H2O + 1 e /
6.500e-10 /
Chem
1 O2-
+ 1 H2O -> 1
O2 + 1 H2O + 1 e /
5.000e-9
0. 5000. / DNA (10-7)
Chem
1 OH- + 1 O3 -> 1 OH + 1 O3- /
5.000e-10 /
Chem
1 OH-
+ 1 O3 -> 1
O2- + 1 HO2 /
1.000e-11 /
Chem
1 H-
+ 1 H2O -> 1
OH- + 1 H2 /
1.000e-09 /
c Ionic Recombination:
Chem
1 H3O+
+ 1 NO2- -> 1
H2O + 1 OH + 1 NO /
1.890e-06 /
Chem
1 H3O+
+ 1 O3- -> 1
H2O + 1 OH + 1 O2 /
1.000e-06 /
c Electron temperature:
Etemp
1 H2O
+ 1 O2 + 1 e -> 1 O2- + 1 H2O
/
1.400e-29 /
c
------------------------------------------------------------------------
c Atomic & Molecular Reactions: Excited State Chemistry
Chem
1 N2a
+ 1 N2a -> 1
N2 + 1 N2+ + 1 e /
1.000e-10 /
Chem
1 N2a
+ 1 O2 -> 1
N2 + 2 O /
2.800e-11 / K92 (#115)
Chem
1 N2a
+ 1 N2 -> 1
N2 + 1 N2 /
2.000e-13 / K92 (#114)
Chem
1 N2a
+ 1 NO -> 1
N2 + 1 N + 1 O /
3.600e-10 / K92 (#116)
c ---------------
Chem
1 N2A
+ 1 N2 -> 1
N2 + 1 N2 /
3.000e-18 / K92 (#105)
Chem
1 N2A
+ 1 O2 -> 1
N2 + 2 O /
1.290e-12 / K92 (#106)
Chem
1 N2A
+ 1 O2 -> 1
N2O + 1 O /
7.800e-14 /
Chem
1 N2A
+ 1 NO -> 1 N2 + 1 NO
/
7.000e-11 / K92 (#109)
Chem
1 N2A
+ 1 O -> 1
NO + 1 N /
7.000e-12 / DNA72 (#32-22)
Chem
1 N2A
+ 1 O -> 1
N2 + 1 O1S /
2.100e-11 / K92 (#108)
Chem
1 N2A
+ 1 N -> 1
N2 + 1 N /
5.000e-11
/ K92 (#107)
Chem
1 N2A
+ 1 N2O -> 1
N2 + 1 N + 1 NO /
1.000e-11 /
c ---------------
Chem
1 O1D
+ 1 N2 -> 1 O + 1 N2 /
1.800e-11
0. -107. / K92 (#144)
Chem
1 O1D
+ 1 O2 -> 1 O + 1 O2B1S /
2.560e-11
0. -67.
/ K92 (#145)
Chem
1 O1D
+ 1 O2 -> 1 O + 1 O2a1D /
1.000e-12 /
Chem
1 O1D
+ 1 NO -> 1 O2 + 1 N /
1.700e-10 / K92 (#149); NIST has 8.5e-11
Chem
1 O1D
+ 1 NO2 -> 1
O2 + 1 NO /
3.000e-10 / NIST
Chem
1 O1D + 1 N2O -> 1 NO + 1 NO /
7.200e-11 / K92 (#150); NIST has 6.7e-11
Chem
1 O1D
+ 1 N2O -> 1 N + 1 NO2 /
2.450e-13 /
NIST; 0.005 x rate with N2 + O2 products
Chem
1 O1D
+ 1 N2O -> 1
N2 + 1 O2 /
4.900e-11 / NIST; K92 (#151) has 4.4e-11
Chem
1 O1D
+ 1 O3 -> 2 O + 1 O2 /
1.200e-10 / K92 (#147) & NIST; little T
dependence
Chem
1 O1D
+ 1 O3 -> 2
O2 /
2.400e-10 / K92 (#148) & NIST; little T
dependence
Chem
1 O1D
+ 1 O3 -> 1 O + 1 O3 /
2.400e-10 / B82
c Chem
c 1 O1D
+ 1 O3 -> 1 O2B1S
+ 1 O2 /
c
3.600e-11 /
c ---------------
Chem
1 O1S
+ 1 NO -> 1
O2 + 1 N /
5.000e-10 /
Chem
1 O1S
+ 1 O2 -> 1
O2 + 1 O /
4.300e-12
0. 850. / K92 (#153, 154)
Chem
1 O1S
+ 1 O3 -> 1
O2 + 1 O + 1 O1D /
2.900e-10 / K92 (#155)
Chem
1 O1S
+ 1 O3 -> 2
O2 /
2.900e-10 / K92 (#156)
Chem
1 O1S
+ 1 O2a1D -> 1
O2 + 1 O1D /
3.600e-11 / K92 (#161)
Chem
1 O1S
+ 1 O2a1D -> 3 O /
3.400e-11 / K92 (#162)
Chem
1 O1S
+ 1 O2a1D -> 1 O + 1 O2B1S /
1.300e-10 / K92 (#163)
Chem
1 O1S
+ 1 O -> 1 O + 1 O1D /
5.000e-11
0. 301.
/ K92 (#164)
c ---------------
Chem
1 O2a1D + 1 N -> 1 O
+ 1 NO /
2.000e-14
0. 600. / K92 (#121)
Chem
1 O2a1D + 1 O
-> 1 O + 1 O2 /
7.000e-16 / K92 (#124)
Chem
1 O2a1D + 1 NO -> 1 NO + 1 O2 /
2.500e-11 / K92 (#126)
Chem
1 O2a1D + 1 O3 -> 2 O2 + 1 O /
6.239e-11
0. 2876. / NIST fit 283-360 K;
c K92 (#119)
has 9.7e-13 0. 1564.
Chem
1 O2a1D + 1 O2
-> 1 O2 + 1 O2 /
2.200e-18
0.8
/ K92 (#123)
Chem
1 O2a1D + 1 N2 -> 1 O2 + 1 N2 /
1.400e-19 / A89; K92 (#122) has 3.e-21
Chem
1 O2a1D + 1 NO -> 1 O + 1 NO2 /
4.880e-18 / NIST
c ---------------
Chem
1 O2B1S + 1 N2 -> 1 O2a1D + 1 N2 /
4.900e-15
0. 253. / K92 (#127)
Chem
1 O2B1S + 1 O2 -> 1 O2a1D + 1 O2 /
3.730e-16
2.4 241. / K92 (#128); A89 has 4.0e-17 @ 298 K
Chem
1 O2B1S + 1 O3 -> 2 O2a1D + 1 O /
1.800e-11 / K92 (#126)
Chem
1 O2B1S + 1 O -> 1 O2
+ 1 O /
8.000e-14 / K92 (#129)
Chem
1 O2B1S + 1 NO -> 1 O2a1D + 1 NO /
4.000e-14 / K92 (#131)
c
------------------------------------------------------------------------
c Ion - Molecule Reactions:
c Positive Ions
Chem
1 O+
+ 1 N2 -> 1
NO+ + 1 N /
3.000e-12 / K92 (#187)
Chem
1 O2+
+ 1 NO -> 1
O2 + 1 NO+ /
4.400e-10 / K92 (#208)
Chem
1 O2+
+ 1 O2 + 1 N2 -> 1 O4+ + 1 N2
/
2.400e-30
-3.2 / K92 (#167) [O2]
Chem
1 O2+
+ 1 O2 + 1 N -> 1 O4+ + 1 N
/
2.400e-30
-3.2 / use
the rate for M = O2
Chem
1 O2+
+ 1 N -> 1 NO+ + 1 O /
1.200e-10 / K92 (#207)
Chem
1 O2+
+ 1 N2 -> 1
NO+ + 1 NO /
1.000e-17 / K92 (#206)
Chem
1 O3+
+ 1 O2 -> 1
O2+ + 1 O3 /
1.000e-11 /
Chem
1 O4+
+ 1 O2a1D -> 1
O2+ + 1 O2 + 1 O2 /
1.000e-10 / K92 (#228)
Chem
1 O4+
+ 1 O2B1S -> 1
O2+ + 1 O2 + 1 O2 /
1.000e-10 / K92 (#228)
Chem
1 O4+
+ 1 NO -> 1
NO+ + 1 O2 + 1 O2 /
1.000e-10 / K92 (#230)
Chem
1 O4+
+ 1 O -> 1
O3 + 1 O2+ /
3.000e-10 / K92 (#229); DNA (14-22)
Chem
1 O4+
+ 1 O -> 1
O3+ + 1 O2 /
3.000e-10 /
Chem
/
1 O4+
+ 1 O -> 1 O2+ + 1 O3 /
3.000e-10 /
Chem
/
1 O4+
+ 1 O2 -> 1
O2+ + 1 O2 + 1 O2 /
2.000e-13 /
c ---------------
Chem
1 N2+
+ 1 O -> 1
N2 + 1 O+ /
1.000e-11
-0.2 / K92 (#199)
Chem
1 N2+
+ 1 O -> 1
NO+ + 1 N /
1.300e-10
-0.5
/ K92 (#198)
Chem
1 N2+
+ 1 O2 -> 1
N2 + 1 O2+ /
6.000e-11
-0.5
/ K92 (#197)
Chem
1 N2+
+ 1 NO -> 1
N2 + 1 NO+ /
3.300e-10 / K92 (#203)
Chem
1 N2+ + 1 N2 + 1 N2 -> 1 N4+ + 1 N2
/
5.000e-29
-1. / DNA72 (#19-6);
also K92 (#165) w/o T dependence
Chem
1 N2+
+ 1 N2 + 1 N -> 1 N4+ + 1 N
/
5.000e-29
-1. / use the rate for M = N2
Chem
/
1 N4+
+ 1 O2 -> 1
O2+ + 1 N2 + 1 N2 /
2.500e-10 /
Chem
/
1 N4+
+ 1 O -> 1
O+ + 1 N2 + 1 N2 /
2.500e-10 /
c Negative Ions
Chem
1 O-
+ 1 N2 -> 1
N2O + 1 e /
1.000e-12 /
Chem
1 O-
+ 1 O2 -> 1
O3 + 1 e /
5.000e-15 / K92 (#72)
Chem
1 O-
+ 1 O -> 1
O2 + 1 e /
5.000e-10 / K92 (#68)
Chem
1 O-
+ 1 N -> 1 NO + 1 e
/
2.600e-10 / K92 (#69)
Chem
1 O-
+ 1 N2A -> 1 O + 1 N2
+ 1 e /
2.200e-9 / K92 (#64)
Chem
1 O-
+ 1 O2a1D -> 1
O3 + 1 e /
3.000e-10 / K92 (#62)
Chem
1 O-
+ 1 O3 -> 2
O2 + 1 e /
5.300e-10 / K92 (#243)
Chem
1 O-
+ 1 NO -> 1
NO2 + 1 e /
2.600e-10 / K92 (#73)
Chem
1 O-
+ 1 N2O -> 1
NO- + 1 NO /
2.100e-10 / K92 (#245)
Chem
1 O-
+ 1 NO2 -> 1 O + 1 NO2- /
1.200e-09 / K92 (#244)
Chem
1 O-
+ 1 NO2 -> 1
O2- + 1 NO /
2.000e-11 /
Chem
1 O-
+ 1 O2 + 1 O2 -> 1 O3- + 1 O2
/
1.100e-30 / K92 (#235)
Chem
1 O-
+ 1 O3 -> 1
O3- + 1 O /
5.500e-10 / SGG87; K92 (#243) has 5.3e-10
Chem
1 O-
+ 1 O3 -> 1
O2- + 1 O2 /
1.000e-11 / SGG87
c ---------------
Chem
1 O2-
+ 1 O -> 1
O- + 1 O2 /
3.310e-10 / K92 (#237)
Chem
1 O2-
+ 1 O -> 1
O3 + 1 e /
1.500e-10 / K92 (#66)
Chem
1 O2-
+ 1 O2 -> 1
O2 + 1 O2 + 1 e /
2.700e-18
0.5 5590. / K92 (#57)
Chem
1 O2-
+ 1 O2a1D -> 1
O2 + 1 O2 + 1 e /
2.000e-10 / K92 (#58)
Chem
1 O2-
+ 1 O2B1S -> 1
O2 + 1 O2 + 1 e /
3.600e-10 / K92 (#59)
Chem
1 O2-
+ 1 N2 -> 1
O2 + 1 N2 + 1 e /
1.100e-19 /
Chem
1 O2-
+ 1 NO2 -> 1
NO2- + 1 O2 /
8.000e-10 / K92 (#239)
Chem
1 O2-
+ 1 N -> 1
NO2 + 1 e /
5.000e-10
/ K92 (#67); DNA72 (#12-11)
Chem
1 O2-
+ 1 O3 -> 1
O2 + 1 O3- /
4.000e-10 / K92 (#239); DNA72 (#15-5)
c ---------------
Chem
1 O3-
+ 1 O -> 1
O2- + 1 O2 /
1.100e-11 / SGG87
Chem
1 O3-
+ 1 O -> 2
O2 + 1 e /
1.400e-10
/ K92 (#70)
Chem
1 O3-
+ 1 N2 -> 1
NO2- + 1 NO /
1.000e-20 / SGG87
Chem
1 O3-
+ 1 NO -> 1
NO3- + 1 O /
1.000e-11 / K92 (#248)
Chem
1 O3-
+ 1 NO2 -> 1
O3 + 1 NO2- /
7.000e-10 / K92 (#250)
Chem
1 O3-
+ 1 NO2 -> 1
NO3- + 1 O2 /
2.000e-11 / K92 (#251)
c ---------------
Chem
1 NO-
+ 1 O2 -> 1
O2- + 1 NO /
5.000e-10 / K92 (#253)
Chem
1 NO-
+ 1 NO2 -> 1
NO2- + 1 NO /
7.400e-16 / K92 (#254)
Chem
1 NO-
+ 1 N2O -> 1 NO2- + 1 N2 /
2.800e-14 / K92 (#255)
Chem
1 NO2-
+ 1 O3 -> 1
O2 + 1 NO3- /
9.000e-11 / SGG87; K92 (#256) has 1.8e-11
c
------------------------------------------------------------------------
c Negative Ion Clusters:
Chem
1 O-
+ 1 H2O + 1 N2 -> 1 H2O2- + 1 N2 /
1.300e-28 /
Chem
1 O-
+ 1 H2O + 1 O2 -> 1 H2O2- + 1 O2 /
1.300e-28 /
Chem
1 O2-
+ 1 H2O + 1 N2 -> 1 H2O3- + 1 N2 /
2.200e-28 /
Chem
/
1 O2-
+ 1 H2O + 1 O2 -> 1 H2O3- + 1 O2 /
2.200e-28 /
Chem
/
1 O3-
+ 1 H2O + 1 N2 -> 1 H2O4- + 1 N2 /
2.700e-28 /
Chem
/
1 O3-
+ 1 H2O + 1 O2 -> 1 H2O4- + 1 O2 /
2.700e-28 /
Chem
/
1 OH-
+ 1 H2O + 1 N2 -> 1 H3O2- + 1 N2 /
2.500e-28 /
Chem /
1 OH-
+ 1 H2O + 1 O2 -> 1 H3O2- + 1 O2 /
2.500e-28 /
Chem /
1 NO-
+ 1 H2O + 1 N2 -> 1 NO-w + 1 N2
/
1.000e-28 /
Chem
/
1 NO-
+ 1 H2O + 1 O2 -> 1 NO-w + 1 O2
/
1.000e-28 /
Chem
/
1 NO2-
+ 1 H2O + 1 N2 -> 1 NO2-w + 1 N2 /
1.600e-28 /
Chem
/
1 NO2-
+ 1 H2O + 1 O2 -> 1 NO2-w + 1 O2 /
1.600e-28 /
c
------------------------------------------------------------------------
c Ionic Recombination of + & -
Clusters:
Chem /
1 H3O+
+ 1 H2O2- -> 2
H2O + 1 OH /
1.000e-06 /
Chem /
1 H3O+
+ 1 H2O3- -> 2
H2O + 1 HO2 /
1.000e-06 /
Chem
/
1 H3O+
+ 1 H2O4- -> 2
H2O + 1 OH + 1 O2 /
1.000e-06 /
Chem
/
1 H3O+
+ 1 H3O2- -> 3 H2O /
1.000e-06 /
Chem
/
1 H3O+
+ 1 NO-w -> 2
H2O + 1 HNO /
1.000e-06 /
Chem
/
1 H3O+
+ 1 NO2-w -> 2
H2O + 1 HNO2 /
1.000e-06 /
c
/
Chem
/
1 OH+
+ 1 H2O2- -> 1
H2O + 1 HO2 /
1.000e-06 /
Chem
/
1 OH+
+ 1 H2O3- -> 1
H2O + 1 OH + 1 O2 /
1.000e-06 /
Chem
/
1 OH+
+ 1 H2O4- -> 1
H2O + 1 HO2 + 1 O2 /
1.000e-06 /
Chem
/
1 OH+
+ 1 H3O2- -> 2
H2O + 1 O /
1.000e-06 /
Chem
/
1 OH+
+ 1 NO-w -> 1
H2O + 1 HNO2 /
1.000e-06 /
Chem /
1 OH+
+ 1 NO2-w -> 1
H2O + 1 HNO3 /
1.000e-06 /
c /
Chem
/
1 O2+
+ 1 H2O2- -> 1
H2O + 1 O3 /
1.000e-06 /
Chem
/
1 O2+
+ 1 H2O3- -> 1
H2O + 2 O2 /
1.000e-06 /
Chem /
1 O2+
+ 1 H2O4- -> 1
H2O + 1 O3 + 1 O2 /
1.000e-06 /
Chem /
1 O2+
+ 1 H3O2- -> 1
H2O2 + 1 HO2 /
1.000e-06 /
Chem /
1 O2+
+ 1 NO-w -> 1
H2O + 1 NO3 /
1.000e-06 /
Chem
/
1 O2+
+ 1 NO2-w -> 1
H2O + 1 NO2 + 1 O2 /
1.000e-06 /
c
/
Chem
/
1 NO+
+ 1 H2O2- -> 1
H2O + 1 NO2 /
1.000e-06 /
Chem
/
1 NO+ + 1 H2O3- -> 1 H2O + 1 NO3 /
1.000e-06 /
Chem
/
1 NO+
+ 1 H2O4- -> 1 H2O + 1 NO2 + 1 O2 /
1.000e-06 /
Chem
/
1 NO+
+ 1 H3O2- -> 1
H2O + 1 HNO2 /
1.000e-06 /
Chem
/
1 NO+
+ 1 NO-w -> 1
H2O + 2 NO /
1.000e-06 /
Chem
/
1 NO+
+ 1 NO2-w -> 1
H2O + 1 NO2 + 1 NO /
1.000e-06 /
Chem
1 O2-
+ 1 NO+ -> 1
O2 + 1 N + 1 O /
1.000e-07 /
Chem
1 O3-
+ 1 O+ -> 1
O3 + 1 O /
2.000e-07 /
Chem
1 O3-
+ 1 O2+ -> 1
O3 + 1 O2 /
2.000e-07 /
Chem
1 O3-
+ 1 O2+ -> 2 O + 1 O3 /
1.000e-07 /
Chem
1 O3-
+ 1 NO+ -> 1
O3 + 1 NO /
2.000e-07
/
Chem
1 NO3-
+ 1 NO+ -> 1
NO3 + 1 N + 1 O /
1.000e-07 /
Chem
1 NO3-
+ 1 O2+ -> 1 NO3 + 1 O + 1 O /
1.000e-07 /
Chem
1 O-
+ 1 O2+ -> 1 O + 1 O2 /
2.000e-07 /
Chem
1 O-
+ 1 O2+ + 1 O2 -> 1 O3 + 1 O2
/
2.000e-25 /
Chem
1 O-
+ 1 NO+ + 1 O2 -> 1 NO2 + 1 O2 /
2.000e-25 /
Chem
1 O2-
+ 1 O2+ -> 1
O2 + 1 O2 /
4.200e-07 /
Chem
1 O2-
+ 1 NO+ + 1 O2 -> 2 O2 + 1 NO
/
2.000e-25 /
c
**********************************************************************
c
Electron Collisions:
Boltz
1 N2 + 1 e -> 1
N2v + 1 e /
N2
N2v1
c
--------------------------------------------------------------
c the V-T rates are V-scaled based on the
P(1,0) transition
c probability shown by Center & Caledonia
(1971)
Chem
1 N2v + 1 Ar -> 1
N2 + 1 Ar / V-T
4.e-20 0.5 /
c
--------------------------------------------------------------
c the following all use the same V-V rate
coefficient based on
c the canonical P(1,0;0,1) V-V transition probability of 10^-3
c from Center & Caledonia (1971)
c Chem
c 2 N2v1 -> 1 N2v2
+ 1 N2 / V-V
c 8.e-11 0.5 /
c
--------------------------------------------------------------
c CO2 chemistry
Boltz
1 CO2 + 1 e -> 1
CO2v + 1 e /
CO2
CO2v
Boltz
1 CO2 + 1 e -> 1
CO + 1 O- /
CO2
CO+O-
Chem
1 O-
+ 1 CO2 + 1 Ar -> 1 CO3- + 1 Ar / negative
ion formation
1.5e-28 / Smirnov (M = He)
Chem
1 O-
+ 2 CO2 -> 1
CO3- + 1 CO2 / negative ion formation
1.e-27 / Smirnov
c
--------------------------------------------------------------
c CO2 chemistry
Chem
1 CO2
+ 1 O -> 1 CO + 1 O2 /
4.285e-11 0. 26710. / NIST, 300-6000 K fit
Chem
1 CO2
+ 1 H -> 1 CO + 1 OH /
4.043e-10 0. 13280. / NIST, 300-3000 K fit
c Chem
c 1 CO2
+ 1 O1D -> 1 CO + 1 O2 /
c 2.e-10 / NIST
Chem
1 CO2
+ 1 O1D -> 1 CO2 + 1 O /
7.4e-11 0. -120.
/ NIST, 200-300 K
Chem
1 CO2
+ 1 O1S -> 1 CO2 + 1 O /
3.1e-11 0. -1320. / McGKG, 200-450 K
c CO chemistry
Chem
1 CO
+ 1 O + 1 N2 -> 1 CO2 + 1 N2 /
1.182e-33 0. 1470. / NIST, 250-4000 K fit
Chem
1 CO
+ 1 O2 -> 1 CO2 + 1 O /
6.57e-12 0. 23940. / NIST, 300-6000 K fit
Chem
1 CO
+ 1 O1D -> 1 CO2 /
7.3e-11
/ NIST (73HEI/HUS)
Chem
1 CO
+ 1 N -> 1 CN + 1 O /
3.83e-9 0. 35990. / NIST (86IBR), 4000-8000 K
Chem
1 CO
+ 1 NO2 -> 1 CO2 + 1 NO /
1.374e-10 0. 16980. / NIST, 298-2000 K fit
Chem
1 CO
+ 1 N2O -> 1 CO2 + 1 N2 /
1.38e-10 0. 20550. / NIST, 1060-2500 K fit
Chem
1 CO
+ 1 H + 1 N2 -> 1 HCO + 1 N2 /
1.9e-33 0. 842. / NIST (84WAR), 300-2500 K
Chem
1 CO
+ 1 OH -> 1 CO2 + 1 H /
2.175e-14 1.812 -593.9 / NIST, 200-2600 K fit
Chem
1 CO
+ 1 HO2 -> 1 CO2 + 1 OH
/
4.744e-10 0. 12230. / NIST, 300-2500 K fit
c Negative Ion chemistry
Chem
1 O-
+ 1 CO -> 1 CO2 + 1 e /
6.e-10 -0.32 /
DNA (12-9); Smirnov
Chem
1 H2O3- + 1 CO2 -> 1 CO4- + 1 H2O
/
5.8e-10 / DNA (16-21)
Chem
1 CO3- + 1 O -> 1 O2- +
1 CO2 /
8.e-11 / DNA (16-22)
Chem
1 CO3- + 1 NO -> 1 NO2- + 1
CO2 /
9.e-12 / DNA (16-23)
Chem
1 CO3- + 1 NO2 -> 1 NO3- + 1 CO2
/
8.e-11 / DNA (16-24)
Chem
1 CO4- + 1 O -> 1 CO3- +
1 O2 /
1.5e-10 / DNA (16-25)
Chem
1 CO4- + 1 O2 -> 1 O4- + 1
CO2 /
4.3e-10 0. 3000. / DNA (16-26)
Chem
1 CO4- + 1 NO -> 1 NO3- + 1
CO2 /
4.8e-11
/ DNA (16-27)
End_List
/