c full N2/O2/H2O/CO2 model; March 1994 c symbol energy yinit MolWt StatWt Csubv ion_Z Q_flag e 0.00 0. 0 1. 1.5 -1 F N2 0.00 0.79 28 1. 2.5 0 T N2v 0.29 0. 28 1. 2.5 0 F N2A 6.17 0.0 28 1. 2.5 0 T N2a 8.40 0.0 28 1. 2.5 0 T N2+ 15.60 0.0 28 1. 2.5 +1 F N4+ 15.60 0.0 56 1. 2.5 +1 F O2 0.00 0.21 32 1. 2.5 0 T O2v 0.00 0.0 32 1. 2.5 0 F O2a1D 0.98 0.0 32 1. 2.5 0 T O2B1S 1.63 0.0 32 1. 2.5 0 T O2+ 12.06 0.0 32 1. 2.5 +1 F O4+ 12.06 0.0 64 1. 2.5 +1 F O2- -0.43 0.0 32 1. 2.5 -1 F O 5.15 0.0 16 1. 1.5 0 T O1D 7.30 0.0 16 1. 1.5 0 F O1S 9.10 0.0 16 1. 1.5 0 F O+ 13.66 0.0 16 1. 1.5 +1 F O- 3.70 0.0 16 1. 1.5 -1 F O3 1.51 0.0 48 1. 2.5 0 T O3- -0.60 0.0 48 1. 2.5 -1 F O3+ 14.31 0.0 48 1. 2.5 +1 F O4- 0. 0.0 64 1. 2.5 -1 F N 9.75 0.0 14 1. 1.5 0 F NO 0.93 0.0 30 1. 2.5 0 F NO+ 9.28 0.0 30 1. 2.5 +1 F NO- 0.91 0.0 30 1. 2.5 -1 F NO2 0.37 0.0 46 1. 2.5 0 F NO2- -2.10 0.0 46 1. 2.5 -1 F NO3 0.74 0.0 62 1. 2.5 0 F NO3- -2.00 0.0 62 1. 2.5 -1 F N2O 0.88 0.0 44 1. 2.5 0 T N2O3 0.86 0.0 76 1. 2.5 0 F H2O -2.51 0.025 18 1. 2.5 0 T H 4.48 0.0 1 1. 1.5 0 F H- 1.49 0.0 1 1. 1.5 -1 F OH 5.12 0.0 17 1. 2.5 0 F OH- -1.43 0.0 17 1. 2.5 -1 F H2 0.00 0.0 2 1. 2.5 0 F H2O+ 12.62 0.0 18 1. 2.5 +1 F H3O+ 4.80 0.0 19 1. 2.5 +1 F OH+ 12.94 0.0 17 1. 2.5 +1 F HO2 0.217 0.0 33 1. 2.5 0 F H2O2 -1.41 0.0 34 1. 2.5 0 F H2O2- 2.9 0.0 34 1. 2.5 -1 F H2O3- -1.23 0.0 50 1. 2.5 -1 F H2O4- -1.4 0.0 66 1. 2.5 -1 F H3O2- -2.50 0.0 35 1. 2.5 -1 F NO-w 0.28 0.0 48 1. 2.5 -1 F NO2-w -2.76 0.0 64 1. 2.5 -1 F NH 0.00 0.0 15 1. 2.5 0 F NH2 0.00 0.0 16 1. 2.5 0 F HNO -0.50 0.0 31 1. 2.5 0 F HNO2 -0.79 0.0 47 1. 2.5 0 F HNO3 -1.40 0.0 63 1. 2.5 0 F CO2 -4.06 0.00 44 1.0 3.5 0 T CO2v -3.977 0. 44 1.0 3.5 0 F CO -1.18 0. 28 1.0 2.5 0 F CO3- 0. 0. 60 1.0 2.5 -1 F CO4- 0. 0. 76 1.0 2.5 -1 F CN 0. 0. 26 1.0 2.5 0 F HCO 0. 0. 29 1.0 2.5 0 F Ar 0.0 0.0 40 1.0 1.5 0 T End_List / c Begining of Air Chemistry: c Electron Processes: c Processes involving solution of Boltzmann's eqn: Boltz / 1 N2 + 1 e -> 1 N2A + 1 e / N2 N2A / Boltz / 1 N2 + 1 e -> 1 N2a + 1 e / N2 N2a / Boltz / 1 N2 + 1 e -> 1 N2+ + 2 e / N2 N2+ / Boltz / 1 O2 + 1 e -> 1 O2+ + 2 e / O2 O2+ / Boltz / 1 O2 + 1 e -> 1 O2a1D + 1 e / O2 O2a1D / Boltz / 1 O2 + 1 e -> 1 O2B1S + 1 e / O2 O2B1S / Boltz / 1 O2 + 1 e -> 1 O + 1 O + 1 e / O2 O+O / Boltz / 1 O2 + 1 e -> 1 O- + 1 O / O2 O+O- / Boltz / 1 O2 + 1 e -> 1 O2- / O2 O2- / Boltz / 1 O + 1 e -> 1 O+ + 2 e / O O+ / Boltz / 1 O + 1 e -> 1 O1D + 1 e / O O1D / Boltz / 1 O + 1 e -> 1 O1S + 1 e / O O1S / Boltz / 1 N2a + 1 e -> 1 N2+ + 2 e / N2a N2+ / Boltz / 1 N2A + 1 e -> 1 N2+ + 2 e / N2A N2+ / Boltz / 1 O2a1D + 1 e -> 1 O + 1 O + 1 e / O2a1D O+O / Boltz / 1 O2a1D + 1 e -> 1 O2+ + 2 e / O2a1D O2+ / Boltz / 1 O2B1S + 1 e -> 1 O + 1 O + 1 e / O2B1S O+O / Boltz / 1 O2B1S + 1 e -> 1 O2+ + 2 e / O2B1S O2+ / Boltz / 1 N2O + 1 e -> 1 N2 + 1 O- / N2O N2+O- / Boltz / 1 O3 + 1 e -> 1 O3+ + 2 e / O3 O3+ / Boltz / 1 H2O + 1 e -> 1 H + 1 OH + 1 e / H2O H+OH / Boltz / 1 H2O + 1 e -> 1 O1D + 1 H2 + 1 e / H2O O*+H2 / Boltz / 1 H2O + 1 e -> 1 H2O+ + 2 e / H2O H2O+ / Boltz / 1 H2O + 1 e -> 1 OH- + 1 H / H2O OH-+H / Boltz / 1 H2O + 1 e -> 1 H- + 1 OH / H2O H-+OH / Boltz / 1 H2O + 1 e -> 1 H2 + 1 O- / H2O H2+O- / c ********************************************************************** c Electron "temperature" dependent processes: / c Recombination: Etemp / 1 e + 1 N2+ -> 1 N + 1 N / 5.400e-08 -0.39 / 2.2e-7 @ 300K Biondi (76) Etemp 1 e + 1 N2+ + 1 O2 -> 1 N2 + 1 O2 / 1.000e-26 / Etemp / 1 e + 1 O2+ -> 1 O + 1 O / 2.700e-08 -0.56 / 2.1e-7 @ 300K Biondi (76) Etemp / 1 e + 1 O2+ -> 1 O + 1 O1D / 1.950e-07 / Etemp 1 e + 1 O2+ + 1 O2 -> 1 O2 + 1 O2 / 8.000e-29 / Etemp / 1 e + 1 NO+ -> 1 N + 1 O / 6.600e-08 -0.5 / 4.1e-7 @ 300K Biondi (76) Etemp / 1 e + 1 NO+ + 1 O2 -> 1 NO + 1 O2 / 3.100e-23 -1.5 / Etemp / 1 e + 1 N4+ -> 1 N2 + 1 N + 1 N / 2.000e-06 / Etemp / 1 e + 1 O4+ -> 1 O2 + 1 O + 1 O / 2.000e-06 / Etemp / 1 e + 1 O4+ -> 1 O2 + 1 O2 / 1.100e-07 / Etemp / 1 e + 1 O+ + 1 e -> 1 O + 1 e / 8.750e-27 -4.5 / CRR Etemp / 1 e + 1 O+ + 1 N2 -> 1 O + 1 N2 / 5.600e-27 -4.5 / CRR Etemp / 1 e + 1 O+ + 1 O2 -> 1 O + 1 O2 / 5.600e-27 -4.5 / CRR Etemp / 1 e + 1 H2O+ -> 1 H + 1 OH / 1.100e-06 -0.5 / 6.6e-6 @ 300K Etemp / 1 e + 1 H2O+ -> 1 O + 1 H2 / 3.800e-07 -0.5 / 2.4e-6 @ 300K Etemp / 1 e + 1 H2O+ -> 1 O + 1 H + 1 H / 4.800e-07 -0.5 / 3.0e-6 @ 300K Etemp / 1 e + 1 H3O+ -> 1 H2O + 1 H / 2.200e-06 -0.08 / 3.0e-6 @ 300K Biondi (82) value for H3O+*(H2O)2 c Attachment: Etemp / 1 e + 1 O2 + 1 O2 -> 1 O2- + 1 O2 / 2.200e-30 / Etemp 1 e + 1 O2 + 1 N2 -> 1 O2- + 1 N2 / 1.000e-31 / K92 (#48) Etemp 1 e + 1 O + 1 O2 -> 1 O- + 1 O2 / 1.000e-31 / Etemp 1 e + 1 O + 1 N2 -> 1 O- + 1 N2 / 1.000e-31 / c Etemp c 1 e + 1 HO2 -> 1 H + 1 O2- / c 5.000e-09 / Etemp 1 e + 1 NO2 -> 1 O- + 1 NO / 3.400e-10 -2.4 3. / McDaniel, V. IV, p. 1472-1473 Etemp 1 e + 1 NO2 -> 1 NO2- / 4.000e-11 / McDaniel, V. IV, p. 1472-1473 Etemp 1 e + 1 O3 -> 1 O- + 1 O2 / 1.000e-11 / c Etemp c 1 e + 1 O -> 1 O- / c 1.300e-15 / Etemp 1 e + 1 O3 + 1 O2 -> 1 O3- + 1 O2 / 4.600e-28 / Etemp 1 e + 1 NO -> 1 O- + 1 N / 3.400e-06 -8.2 15.2 / McDaniel, V. IV, p. 1472-1473 Etemp 1 e + 1 NO + 1 N2 -> 1 NO- + 1 N2 / 4.000e-29 / Smirnov, p. 117; k=4x10^-11 for [N2]=10^18 Etemp 1 e + 1 HNO2 -> 1 NO2- + 1 H / 5.000e-08 / McDaniel, V. IV, p. 1472-1473 Etemp 1 e + 1 HNO3 -> 1 NO2- + 1 OH / 5.000e-08 / McDaniel, V. IV, p. 1472-1473 c Etemp c 1 e + 1 N2O + 1 N2 -> 1 N2O- + 1 N2 / c 0.030e-31 / Smirnov, p. 117 c Dissociation: Etemp 1 e + 1 O3 -> 1 O2 + 1 O + 1 e / 2.240e-08 / c ********************************************************************** c Atomic & Molecular Reactions: Neutral Chemistry Chem 1 O + 1 O + 1 N2 -> 1 O2 + 1 N2 / 6.498e-35 0. -1039. / NIST fit 196-5000 K c K92 (#91): 2.76e-34 0. -720. Chem 1 O + 1 O + 1 N -> 1 O2 + 1 N / 6.498e-35 0. -1039. / use the rate for M = N2 Chem 1 O + 1 O2 + 1 O2 -> 1 O3 + 1 O2 / 2.413e-34 -1.029 -238.9 / NIST fit 80-3000 K; K92 (#95) has c 6.9e-34 -1.25 0.0 Chem 1 O + 1 O2 + 1 N2 -> 1 O3 + 1 N2 / 2.413e-34 -1.029 -238.9 / NIST fit 80-3000 K; K92 (#94) has c 6.2e-34 -2.0 0.0 Chem 1 O + 1 O2 + 1 O3 -> 1 O3 + 1 O3 / 1.430e-33 -2. / SGG87 Chem 1 O + 1 O2 + 1 O -> 1 O3 + 1 O / 2.150e-34 0. -345. / SGG87 Chem 1 O + 1 O3 -> 2 O2 / 1.529e-11 0. 2185. / NIST fit 197-2000 K c K92 (#82): 2.0e-11 0. -2300. Chem 1 O + 1 NO + 1 N2 -> 1 NO2 + 1 N2 / 1.064e-31 -1.682 46.26 / NIST fit 200-3000 K; see also K92 (#96) Chem 1 O + 1 NO + 1 O2 -> 1 NO2 + 1 O2 / 1.064e-31 -1.682 46.26 / NIST fit 200-3000 K; see also K92 (#96) Chem 1 O + 1 NO -> 1 NO2 / 2.221e-11 0.459 -92.64 / NIST fit 200-1500 K Chem 1 O + 1 NO -> 1 O2 + 1 N / 4.222e-11 0.0 23200. / NIST fit 1500-5000 K Chem 1 O + 1 NO + 1 N2 -> 1 NO2 + 1 N2 / 1.064e-31 -1.682 46.26 / NIST fit 200-3000 K Chem 1 O + 1 NO2 -> 1 O2 + 1 NO / 9.090e-12 0.18 / K92 (#81) c Chem c 1 O + 1 NO2 -> 1 NO3 / c 2.200e-11 / NIST fit; 200-400 K Chem 1 O + 1 NO2 + 1 N2 -> 1 NO3 + 1 N2 / 1.065e-31 -2.157 46.59 / NIST fit; 200-400 K Chem 1 O + 1 NO2 + 1 O2 -> 1 NO3 + 1 O2 / 1.065e-31 -2.157 46.59 / NIST fit 200-400 K; see K92 (#97) Chem 1 O + 1 NO2 + 1 N2 -> 1 NO3 + 1 N2 / 1.065e-31 -2.157 46.59 / NIST fit 200-400 K; see K92 (#97) Chem 1 O + 1 NO3 -> 1 O2 + 1 NO2 / 1.000e-11 / K92 (#83); NIST c --------------- Chem 1 N + 1 N + 1 N2 -> 1 N2 + 1 N2 / 8.270e-34 0. -500. / K92 (#90) c NIST: ref 91PRA/SMI has k = 4.1e-34, 8.6e-34, 1.1e-33 for c M = He, Ar, Xe respectively @ 293 K Chem 1 N + 1 N + 1 N -> 1 N2 + 1 N / 23.320e-34 0. -500. / use rate coefficient for M = N2 c but multiplied by 2.82 to reflect the measurement of 1.25e-32 c by ref 88KNI/RUB listed in the NIST database Chem 1 N + 1 NO -> 1 N2 + 1 O / 3.513e-11 0. 49.84 / NIST fit 196-3000 K; see K92 (#76) Chem 1 N + 1 O2 -> 1 NO + 1 O / 1.001e-11 0. 3473. / NIST fit 200-1000 K; see K92 (#74) Chem 1 N + 1 NO2 -> 1 N2O + 1 O / 3.000e-12 / K92 (#79); NIST too Chem 1 N + 1 O3 -> 1 NO + 1 O2 / 1.000e-16 / NIST; K92 (#75) has k <= 2.e-16 c --------------- Chem 1 NO + 1 O3 -> 1 O2 + 1 NO2 / 4.300e-12 0. 1560. / K92 (#85) c the 195-500 K fit from the NIST database is 2.445e-12 0. 1446. Chem 1 NO2 + 1 O3 -> 1 NO3 + 1 O2 / 1.893e-13 0. 2542. / NIST fit 200-363 K; K92 (#87) has Chem 1 NO3 + 1 O3 -> 2 O2 + 1 NO2 / 1.000e-17 / NIST c 1.2e-13 0. 2450. c --------------- Chem 1 NO + 1 NO2 + 1 N2 -> 1 N2O3 + 1 N2 / 9.110e-33 / NIST c Chem c 1 NO + 1 NO2 -> 1 N2O3 / c 3.400e-12 / NIST Chem 1 NO + 1 NO3 -> 2 NO2 / 1.113e-11 0. -220.9 / NIST fit 200-1100 K; K92 (#86) has 1.7e-11 c ------------------- Humid Air Chemistry Starts Here --------------------- c Neutral Chemistry: Chem 1 H + 1 O2 -> 1 O + 1 OH / 1.168e-10 0.2789 7860. / NIST fit 250-5300 K Chem 1 H + 1 O2 + 1 H2 -> 1 HO2 + 1 H2 / 5.790e-32 -0.8 0. / NIST (84WAR) 300-2500 K Chem 1 H + 1 O2 + 1 N2 -> 1 HO2 + 1 N2 / 5.940e-32 -1.0 0. / NIST (86TSA/HAM) 300-2500 K Chem 1 H + 1 O2 + 1 O2 -> 1 HO2 + 1 O2 / 5.940e-32 -1.0 0. / NIST use rate coeff for M = N2 c note that the rate coefficient for M = Ar is lower: 2.032e-32 -0.8 0. Chem 1 H + 1 OH + 1 N2 -> 1 H2O + 1 N2 / 6.880e-31 -2. 0. / NIST (86TSA/HAM) 300-3000 K Chem 1 H + 1 OH + 1 O2 -> 1 H2O + 1 O2 / 6.880e-31 -2. 0. / use value for M = N2 Chem 1 H + 1 OH + 1 H2O -> 1 H2O + 1 H2O / 4.360e-30 -2. 0. / NIST (84WAR) 1000-3000 K Chem 1 H + 1 NO2 -> 1 NO + 1 OH / 2.200e-10 0. 182. / NIST (91KO/FON) 296-760 K Chem 1 H + 1 O3 -> 1 O2 + 1 OH / 7.788e-11 0.2551 327.8 / NIST fit 196-2000 K Chem 1 H + 1 O3 -> 1 HO2 + 1 O / 7.500e-13 / NIST (79FIN/KLE); k <= 7.5e-13 Chem 1 H + 1 HO2 -> 1 H2 + 1 O2 / 2.571e-11 0.5598 346. / NIST fit 245-2500 K Chem 1 H + 1 HO2 -> 1 OH + 1 OH / 2.356e-10 0. 373.7 / NIST fit 245-2500 K Chem 1 H + 1 HO2 -> 1 H2O + 1 O / 9.180e-11 0. 971.9 / NIST fit 245-773 K c Chem c 1 H + 1 O2 -> 1 HO2 / c 7.500e-11 / NIST (87DEM/GOL) c Chem c 1 H + 1 OH -> 1 H2O / c 2.700e-14 / NIST (77ZEL/ERL) @ 300 K; (72FRI/SUT) has 7.3e-14 @ 2130 K Chem 1 H + 1 HNO -> 1 H2 + 1 NO / 4.270e-12 0. -998.1 / NIST fit 295-2100 K Chem 1 H + 1 HNO -> 1 OH + 1 NH / 2.410e-9 -0.5 9010. / NIST fit 359-3000 K Chem 1 H + 1 HNO -> 1 O + 1 NH2 / 1.050e-9 -0.3 14730. / NIST (91COH/WES) 550-3000 K Chem 1 H + 1 NO -> 1 NH + 1 O / 9.290e-10 -0.10 35220. / NIST (91COH/WES) 1300-3000 K Chem 1 H + 1 NO -> 1 OH + 1 N / 2.111e-10 0.0 24330. / NIST fit 1750-4500 K Chem 1 H + 1 NO + 1 N2 -> 1 HNO + 1 N2 / 7.327e-32 -1.318 184.3 / NIST fit 231-704 K Chem 1 H + 1 NO + 1 O2 -> 1 HNO + 1 O2 / 7.327e-32 -1.318 184.3 / NIST fit 231-704 K Chem 1 H + 1 NO3 -> 1 NO2 + 1 OH / 1.100e-10 / NIST (88BOO/CAN) Chem 1 H + 1 H2O2 -> 1 OH + 1 H2O / 4.000e-11 0. 2000. / NIST (86TSA/HAM) 300-2500 K Chem 1 H + 1 H2O2 -> 1 H2 + 1 HO2 / 8.000e-11 0. 4000. / NIST (86TSA/HAM) 300-2500 K c --------------- Chem 1 OH + 1 OH -> 1 H2O + 1 O / 1.549e-13 1.408 -267.3 / NIST fit 200-2500 K Chem 1 OH + 1 O -> 1 O2 + 1 H / 2.105e-11 -0.186 153.9 / NIST fit 200-5000 K Chem 1 OH + 1 H -> 1 H2 + 1 O / 1.123e-14 3.406 1233. / NIST fit 298-2500 K Chem 1 OH + 1 H2 -> 1 H2O + 1 H / 2.313e-12 1.47 1761. / NIST fit 200-3000 K Chem 1 OH + 1 O3 -> 1 HO2 + 1 O2 / 1.472e-12 0. 932.7 / NIST fit 200-450 K Chem 1 OH + 1 HO2 -> 1 H2O + 1 O2 / 4.381e-11 0. -110.9 / NIST fit 200-2550 K Chem 1 OH + 1 OH + 1 N2 -> 1 H2O2 + 1 N2 / 6.050e-31 -3. 0. / NIST (86TSA/HAM) 300-2500 K; the general fit c is 1.543e-31 -2.021 -183.6 over 200-2500 K Chem 1 OH + 1 OH + 1 O2 -> 1 H2O2 + 1 O2 / 6.050e-31 -3. 0. / NIST (86TSA/HAM) 300-2500 K; same as M = N2 Chem 1 OH + 1 OH + 1 H2O -> 1 H2O2 + 1 H2O / 1.543e-31 -2.021 -183.6 / use general fit from NIST; c NIST ref 88ZEL/EWI have 4.e-30 at 300 K Chem 1 OH + 1 H2O2 -> 1 H2O + 1 HO2 / 4.529e-12 0. 288.9 / NIST fit 200-2500 K Chem 1 OH + 1 HNO2 -> 1 H2O + 1 NO2 / 1.800e-11 0. 390. / NIST (89ATK/BAU) 280-430 K Chem 1 OH + 1 N2O -> 1 HO2 + 1 N2 / 3.696e-13 0. 2740. / NIST fit 298-2700 K c Chem c 1 OH + 1 OH -> 1 H2O2 / c 1.510e-11 -0.37 0. / NIST (87BRO/COB) 200-1500 K Chem 1 OH + 1 NO + 1 N2 -> 1 HNO2 + 1 N2 / 3.924e-32 0. -794.2 / NIST fit 200-505 K Chem 1 OH + 1 NO + 1 O2 -> 1 HNO2 + 1 O2 / 3.924e-32 0. -794.2 / NIST fit 200-505 K Chem 1 OH + 1 NO2 -> 1 HO2 + 1 NO / 3.300e-11 0. 3360. / NIST (80HOW) 452-1115 K Chem 1 OH + 1 NO2 + 1 N2 -> 1 HNO3 + 1 N2 / 8.378e-30 -3.878 409.3 / NIST fit 200-1200 K Chem 1 OH + 1 NO2 + 1 O2 -> 1 HNO3 + 1 O2 / 8.378e-30 -3.878 409.3 / NIST fit 200-1200 K Chem 1 OH + 1 NO3 -> 1 HO2 + 1 NO2 / 2.300e-11 / NIST (89ATK/BAU) Chem 1 OH + 1 HNO -> 1 H2O + 1 NO / 1.266e-11 0.9904 334.2 / NIST fit 298-4000 K Chem 1 OH + 1 HNO3 -> 1 H2O + 1 NO3 / 4.006e-14 0. -317.6 / NIST fit 200-1100 K c --------------- Chem 1 HO2 + 1 O3 -> 1 OH + 2 O2 / 1.752e-15 0. -628.3 / NIST fit 200-413 K Chem 1 HO2 + 1 HO2 -> 1 H2O2 + 1 O2 / 3.000e-12 / NIST (86TSA/HAM) 300-2500 K Chem 1 HO2 + 1 O -> 1 OH + 1 O2 / 2.900e-11 0. -200. / NIST (86TSA/HAM) 300-2500 K Chem 1 HO2 + 1 NO -> 1 OH + 1 NO2 / 3.600e-12 0. -240. / NIST (89ATK/BAU) 230-500 K c & (84HAN/SAL) 1000-2000 K Chem 2 HO2 + 1 N2 -> 1 H2O2 + 1 O2 + 1 N2 / 1.900e-33 0. -980. / NIST (89ATK/BAU) 230-420 K Chem 1 HO2 + 1 HO2 + 1 O2 -> 1 H2O2 + 2 O2 / 1.900e-33 0. -980. / use rate coeff for M = N2 Chem 1 HO2 + 1 NO -> 1 O2 + 1 HNO / 9.100e-19 0. -2819. / NIST (79HOW) 271-303 K Chem 1 HO2 + 1 NO -> 1 OH + 1 NO2 / 3.500e-12 0. -240. / NIST (89ATK/BAU) 230-2000 K Chem 1 HO2 + 1 NO2 -> 1 HNO2 + 1 O2 / 1.200e-13 / NIST (75COX) c Chem c 1 HO2 + 1 NO -> 1 HNO3 / c 1.400e-13 / NIST (75COX/DER) Chem 1 HO2 + 1 N -> 1 OH + 1 NO / 2.200e-11 / NIST (83BRU/SCH2); 1 entry Chem 1 HO2 + 1 NO3 -> 1 HNO3 + 1 O2 / 9.210e-13 / NIST; for O2 + prod on RHS, k=4.3e-12 (89ATK/BAU) c --------------- Chem 1 N + 1 OH -> 1 NO + 1 H / 3.917e-11 0. -72.36 / NIST fit 250-515 K Chem 1 N + 1 OH -> 1 O + 1 NH / 1.880e-11 0.1 10700. / NIST (91COH/WES) 500-3000 K Chem 1 O + 1 H2 -> 1 OH + 1 H / 1.501e-13 2.844 2834. / NIST fit 293-3532 K Chem 1 O + 1 H2O2 -> 1 OH + 1 HO2 / 1.792e-13 2.919 1394. / NIST fit 200-2500 K Chem 1 N2O3 + 1 H2O -> 2 HNO2 / 6.300e-11 0. 4468. / NIST (75ENG/COR) 298-323 K Chem 1 HNO2 + 1 O -> 1 OH + 1 NO2 / 1.000e-15 / NIST (78KAI/JAP2) k <= 1.e-15 Chem 1 HNO3 + 1 O -> 1 OH + 1 NO3 / 3.000e-17 / NIST; k<= 3.e-17 Chem 1 HNO2 + 1 NO3 -> 1 HNO3 + 1 NO2 / 2.000e-15 / NIST (1 entry); k<= 2.e-15 Chem 1 H2O2 + 1 NO3 -> 1 HO2 + 1 HNO3 / 2.000e-15 / NIST (1 entry); k<= 2.e-15 c Excited State Chemistry: Chem 1 N2A + 1 H2O -> 1 H2 + 1 N + 1 NO / 1.000e-10 / Chem 1 N2a + 1 H2O -> 1 H2 + 1 N + 1 NO / 1.000e-10 / c --------------- Chem 1 O1D + 1 H2O -> 1 OH + 1 OH / 2.000e-10 / A89 Chem 1 O1D + 1 H2 -> 1 OH + 1 H / 1.000e-10 / NIST; no T dependence 200-350 K Chem 1 O1D + 1 H2O -> 1 H2 + 1 O2 / 2.300e-10 / NIST Chem 1 O1D + 1 H2O2 -> 1 H2O + 1 O2 / 5.200e-10 / NIST (76FLE/HUS) c --------------- Chem 1 O1S + 1 H2O -> 1 O + 1 H2O / 3.000e-10 / S&B78 Chem 1 O1S + 1 H2O -> 1 OH + 1 OH / 5.000e-10 / S&B78 Chem 1 O1S + 1 H2O -> 1 H2 + 1 O2 / 5.000e-10 / S&B78 c --------------- Chem 1 O2a1D + 1 H2O -> 1 O2 + 1 H2O / 5.000e-18 / Chem 1 O2B1S + 1 H2O -> 1 O2 + 1 H2O / 4.000e-12 / c Ion - Molecule: c Positive Ion Chem 1 O+ + 1 H2 -> 1 OH+ + 1 H / 1.000e-10 / A93 Chem 1 O+ + 1 H2O -> 1 H2O+ + 1 O / 2.600e-09 / A93 Chem 1 O2+ + 2 H2O -> 1 H3O+ + 1 OH + 1 O2 / 2.000e-28 / Chem 1 O4+ + 2 H2O -> 1 H3O+ + 1 OH + 2 O2 / 2.000e-28 / Chem 1 N2+ + 1 H2O -> 1 H2O+ + 1 N2 / 2.200e-09 / A93 Chem 1 H2O+ + 1 O2 -> 1 H2O + 1 O2+ / 3.300e-10 / A93 Chem 1 H2O+ + 1 H2O -> 1 H3O+ + 1 OH / 1.850e-09 / A93 Chem 1 OH+ + 1 O2 -> 1 OH + 1 O2+ / 3.800e-10 / A93 Chem 1 NO+ + 2 H2O -> 1 H3O+ + 1 HNO2 / 2.000e-28 / c Negative Ion Chem 1 O- + 1 H2 -> 1 H2O + 1 e / 6.500e-10 / Chem 1 O2- + 1 H2O -> 1 O2 + 1 H2O + 1 e / 5.000e-9 0. 5000. / DNA (10-7) Chem 1 OH- + 1 O3 -> 1 OH + 1 O3- / 5.000e-10 / Chem 1 OH- + 1 O3 -> 1 O2- + 1 HO2 / 1.000e-11 / Chem 1 H- + 1 H2O -> 1 OH- + 1 H2 / 1.000e-09 / c Ionic Recombination: Chem 1 H3O+ + 1 NO2- -> 1 H2O + 1 OH + 1 NO / 1.890e-06 / Chem 1 H3O+ + 1 O3- -> 1 H2O + 1 OH + 1 O2 / 1.000e-06 / c Electron temperature: Etemp 1 H2O + 1 O2 + 1 e -> 1 O2- + 1 H2O / 1.400e-29 / c ------------------------------------------------------------------------ c Atomic & Molecular Reactions: Excited State Chemistry Chem 1 N2a + 1 N2a -> 1 N2 + 1 N2+ + 1 e / 1.000e-10 / Chem 1 N2a + 1 O2 -> 1 N2 + 2 O / 2.800e-11 / K92 (#115) Chem 1 N2a + 1 N2 -> 1 N2 + 1 N2 / 2.000e-13 / K92 (#114) Chem 1 N2a + 1 NO -> 1 N2 + 1 N + 1 O / 3.600e-10 / K92 (#116) c --------------- Chem 1 N2A + 1 N2 -> 1 N2 + 1 N2 / 3.000e-18 / K92 (#105) Chem 1 N2A + 1 O2 -> 1 N2 + 2 O / 1.290e-12 / K92 (#106) Chem 1 N2A + 1 O2 -> 1 N2O + 1 O / 7.800e-14 / Chem 1 N2A + 1 NO -> 1 N2 + 1 NO / 7.000e-11 / K92 (#109) Chem 1 N2A + 1 O -> 1 NO + 1 N / 7.000e-12 / DNA72 (#32-22) Chem 1 N2A + 1 O -> 1 N2 + 1 O1S / 2.100e-11 / K92 (#108) Chem 1 N2A + 1 N -> 1 N2 + 1 N / 5.000e-11 / K92 (#107) Chem 1 N2A + 1 N2O -> 1 N2 + 1 N + 1 NO / 1.000e-11 / c --------------- Chem 1 O1D + 1 N2 -> 1 O + 1 N2 / 1.800e-11 0. -107. / K92 (#144) Chem 1 O1D + 1 O2 -> 1 O + 1 O2B1S / 2.560e-11 0. -67. / K92 (#145) Chem 1 O1D + 1 O2 -> 1 O + 1 O2a1D / 1.000e-12 / Chem 1 O1D + 1 NO -> 1 O2 + 1 N / 1.700e-10 / K92 (#149); NIST has 8.5e-11 Chem 1 O1D + 1 NO2 -> 1 O2 + 1 NO / 3.000e-10 / NIST Chem 1 O1D + 1 N2O -> 1 NO + 1 NO / 7.200e-11 / K92 (#150); NIST has 6.7e-11 Chem 1 O1D + 1 N2O -> 1 N + 1 NO2 / 2.450e-13 / NIST; 0.005 x rate with N2 + O2 products Chem 1 O1D + 1 N2O -> 1 N2 + 1 O2 / 4.900e-11 / NIST; K92 (#151) has 4.4e-11 Chem 1 O1D + 1 O3 -> 2 O + 1 O2 / 1.200e-10 / K92 (#147) & NIST; little T dependence Chem 1 O1D + 1 O3 -> 2 O2 / 2.400e-10 / K92 (#148) & NIST; little T dependence Chem 1 O1D + 1 O3 -> 1 O + 1 O3 / 2.400e-10 / B82 c Chem c 1 O1D + 1 O3 -> 1 O2B1S + 1 O2 / c 3.600e-11 / c --------------- Chem 1 O1S + 1 NO -> 1 O2 + 1 N / 5.000e-10 / Chem 1 O1S + 1 O2 -> 1 O2 + 1 O / 4.300e-12 0. 850. / K92 (#153, 154) Chem 1 O1S + 1 O3 -> 1 O2 + 1 O + 1 O1D / 2.900e-10 / K92 (#155) Chem 1 O1S + 1 O3 -> 2 O2 / 2.900e-10 / K92 (#156) Chem 1 O1S + 1 O2a1D -> 1 O2 + 1 O1D / 3.600e-11 / K92 (#161) Chem 1 O1S + 1 O2a1D -> 3 O / 3.400e-11 / K92 (#162) Chem 1 O1S + 1 O2a1D -> 1 O + 1 O2B1S / 1.300e-10 / K92 (#163) Chem 1 O1S + 1 O -> 1 O + 1 O1D / 5.000e-11 0. 301. / K92 (#164) c --------------- Chem 1 O2a1D + 1 N -> 1 O + 1 NO / 2.000e-14 0. 600. / K92 (#121) Chem 1 O2a1D + 1 O -> 1 O + 1 O2 / 7.000e-16 / K92 (#124) Chem 1 O2a1D + 1 NO -> 1 NO + 1 O2 / 2.500e-11 / K92 (#126) Chem 1 O2a1D + 1 O3 -> 2 O2 + 1 O / 6.239e-11 0. 2876. / NIST fit 283-360 K; c K92 (#119) has 9.7e-13 0. 1564. Chem 1 O2a1D + 1 O2 -> 1 O2 + 1 O2 / 2.200e-18 0.8 / K92 (#123) Chem 1 O2a1D + 1 N2 -> 1 O2 + 1 N2 / 1.400e-19 / A89; K92 (#122) has 3.e-21 Chem 1 O2a1D + 1 NO -> 1 O + 1 NO2 / 4.880e-18 / NIST c --------------- Chem 1 O2B1S + 1 N2 -> 1 O2a1D + 1 N2 / 4.900e-15 0. 253. / K92 (#127) Chem 1 O2B1S + 1 O2 -> 1 O2a1D + 1 O2 / 3.730e-16 2.4 241. / K92 (#128); A89 has 4.0e-17 @ 298 K Chem 1 O2B1S + 1 O3 -> 2 O2a1D + 1 O / 1.800e-11 / K92 (#126) Chem 1 O2B1S + 1 O -> 1 O2 + 1 O / 8.000e-14 / K92 (#129) Chem 1 O2B1S + 1 NO -> 1 O2a1D + 1 NO / 4.000e-14 / K92 (#131) c ------------------------------------------------------------------------ c Ion - Molecule Reactions: c Positive Ions Chem 1 O+ + 1 N2 -> 1 NO+ + 1 N / 3.000e-12 / K92 (#187) Chem 1 O2+ + 1 NO -> 1 O2 + 1 NO+ / 4.400e-10 / K92 (#208) Chem 1 O2+ + 1 O2 + 1 N2 -> 1 O4+ + 1 N2 / 2.400e-30 -3.2 / K92 (#167) Chem 1 O2+ + 1 O2 + 1 N -> 1 O4+ + 1 N / 2.400e-30 -3.2 / use the rate for M = N2 Chem 1 O2+ + 1 N -> 1 NO+ + 1 O / 1.200e-10 / K92 (#207) Chem 1 O2+ + 1 N2 -> 1 NO+ + 1 NO / 1.000e-17 / K92 (#206) Chem 1 O3+ + 1 O2 -> 1 O2+ + 1 O3 / 1.000e-11 / Chem 1 O4+ + 1 O2a1D -> 1 O2+ + 1 O2 + 1 O2 / 1.000e-10 / K92 (#228) Chem 1 O4+ + 1 O2B1S -> 1 O2+ + 1 O2 + 1 O2 / 1.000e-10 / K92 (#228) Chem 1 O4+ + 1 NO -> 1 NO+ + 1 O2 + 1 O2 / 1.000e-10 / K92 (#230) Chem 1 O4+ + 1 O -> 1 O3 + 1 O2+ / 3.000e-10 / K92 (#229); DNA (14-22) Chem 1 O4+ + 1 O -> 1 O3+ + 1 O2 / 3.000e-10 / Chem / 1 O4+ + 1 O -> 1 O2+ + 1 O3 / 3.000e-10 / Chem / 1 O4+ + 1 O2 -> 1 O2+ + 1 O2 + 1 O2 / 2.000e-13 / c --------------- Chem 1 N2+ + 1 O -> 1 N2 + 1 O+ / 1.000e-11 -0.2 / K92 (#199) Chem 1 N2+ + 1 O -> 1 NO+ + 1 N / 1.300e-10 -0.5 / K92 (#198) Chem 1 N2+ + 1 O2 -> 1 N2 + 1 O2+ / 6.000e-11 -0.5 / K92 (#197) Chem 1 N2+ + 1 NO -> 1 N2 + 1 NO+ / 3.300e-10 / K92 (#203) Chem 1 N2+ + 1 N2 + 1 N2 -> 1 N4+ + 1 N2 / 5.000e-29 -1. / DNA72 (#19-6); also K92 (#165) w/o T dependence Chem 1 N2+ + 1 N2 + 1 N -> 1 N4+ + 1 N / 5.000e-29 -1. / use the rate for M = N2 Chem / 1 N4+ + 1 O2 -> 1 O2+ + 1 N2 + 1 N2 / 2.500e-10 / Chem / 1 N4+ + 1 O -> 1 O+ + 1 N2 + 1 N2 / 2.500e-10 / c Negative Ions Chem 1 O- + 1 N2 -> 1 N2O + 1 e / 1.000e-12 / Chem 1 O- + 1 O2 -> 1 O3 + 1 e / 5.000e-15 / K92 (#72) Chem 1 O- + 1 O -> 1 O2 + 1 e / 5.000e-10 / K92 (#68) Chem 1 O- + 1 N -> 1 NO + 1 e / 2.600e-10 / K92 (#69) Chem 1 O- + 1 N2A -> 1 O + 1 N2 + 1 e / 2.200e-9 / K92 (#64) Chem 1 O- + 1 O2a1D -> 1 O3 + 1 e / 3.000e-10 / K92 (#62) Chem 1 O- + 1 O3 -> 2 O2 + 1 e / 5.300e-10 / K92 (#243) Chem 1 O- + 1 NO -> 1 NO2 + 1 e / 2.600e-10 / K92 (#73) Chem 1 O- + 1 N2O -> 1 NO- + 1 NO / 2.100e-10 / K92 (#245) Chem 1 O- + 1 NO2 -> 1 O + 1 NO2- / 1.200e-09 / K92 (#244) Chem 1 O- + 1 NO2 -> 1 O2- + 1 NO / 2.000e-11 / Chem 1 O- + 1 O2 + 1 O2 -> 1 O3- + 1 O2 / 1.100e-30 / K92 (#235) Chem 1 O- + 1 O3 -> 1 O3- + 1 O / 5.500e-10 / SGG87; K92 (#243) has 5.3e-10 Chem 1 O- + 1 O3 -> 1 O2- + 1 O2 / 1.000e-11 / SGG87 c --------------- Chem 1 O2- + 1 O -> 1 O- + 1 O2 / 3.310e-10 / K92 (#237) Chem 1 O2- + 1 O -> 1 O3 + 1 e / 1.500e-10 / K92 (#66) Chem 1 O2- + 1 O2 -> 1 O2 + 1 O2 + 1 e / 2.700e-18 0.5 5590. / K92 (#57) Chem 1 O2- + 1 O2a1D -> 1 O2 + 1 O2 + 1 e / 2.000e-10 / K92 (#58) Chem 1 O2- + 1 O2B1S -> 1 O2 + 1 O2 + 1 e / 3.600e-10 / K92 (#59) Chem 1 O2- + 1 N2 -> 1 O2 + 1 N2 + 1 e / 1.100e-19 / Chem 1 O2- + 1 NO2 -> 1 NO2- + 1 O2 / 8.000e-10 / K92 (#239) Chem 1 O2- + 1 N -> 1 NO2 + 1 e / 5.000e-10 / K92 (#67); DNA72 (#12-11) Chem 1 O2- + 1 O3 -> 1 O2 + 1 O3- / 4.000e-10 / K92 (#239); DNA72 (#15-5) c --------------- Chem 1 O3- + 1 O -> 1 O2- + 1 O2 / 1.100e-11 / SGG87 Chem 1 O3- + 1 O -> 2 O2 + 1 e / 1.400e-10 / K92 (#70) Chem 1 O3- + 1 N2 -> 1 NO2- + 1 NO / 1.000e-20 / SGG87 Chem 1 O3- + 1 NO -> 1 NO3- + 1 O / 1.000e-11 / K92 (#248) Chem 1 O3- + 1 NO2 -> 1 O3 + 1 NO2- / 7.000e-10 / K92 (#250) Chem 1 O3- + 1 NO2 -> 1 NO3- + 1 O2 / 2.000e-11 / K92 (#251) c --------------- Chem 1 NO- + 1 O2 -> 1 O2- + 1 NO / 5.000e-10 / K92 (#253) Chem 1 NO- + 1 NO2 -> 1 NO2- + 1 NO / 7.400e-16 / K92 (#254) Chem 1 NO- + 1 N2O -> 1 NO2- + 1 N2 / 2.800e-14 / K92 (#255) Chem 1 NO2- + 1 O3 -> 1 O2 + 1 NO3- / 9.000e-11 / SGG87; K92 (#256) has 1.8e-11 c ------------------------------------------------------------------------ c Negative Ion Clusters: Chem 1 O- + 1 H2O + 1 N2 -> 1 H2O2- + 1 N2 / 1.300e-28 / Chem 1 O- + 1 H2O + 1 O2 -> 1 H2O2- + 1 O2 / 1.300e-28 / Chem 1 O2- + 1 H2O + 1 N2 -> 1 H2O3- + 1 N2 / 2.200e-28 / Chem / 1 O2- + 1 H2O + 1 O2 -> 1 H2O3- + 1 O2 / 2.200e-28 / Chem / 1 O3- + 1 H2O + 1 N2 -> 1 H2O4- + 1 N2 / 2.700e-28 / Chem / 1 O3- + 1 H2O + 1 O2 -> 1 H2O4- + 1 O2 / 2.700e-28 / Chem / 1 OH- + 1 H2O + 1 N2 -> 1 H3O2- + 1 N2 / 2.500e-28 / Chem / 1 OH- + 1 H2O + 1 O2 -> 1 H3O2- + 1 O2 / 2.500e-28 / Chem / 1 NO- + 1 H2O + 1 N2 -> 1 NO-w + 1 N2 / 1.000e-28 / Chem / 1 NO- + 1 H2O + 1 O2 -> 1 NO-w + 1 O2 / 1.000e-28 / Chem / 1 NO2- + 1 H2O + 1 N2 -> 1 NO2-w + 1 N2 / 1.600e-28 / Chem / 1 NO2- + 1 H2O + 1 O2 -> 1 NO2-w + 1 O2 / 1.600e-28 / c ------------------------------------------------------------------------ c Ionic Recombination of + & - Clusters: Chem / 1 H3O+ + 1 H2O2- -> 2 H2O + 1 OH / 1.000e-06 / Chem / 1 H3O+ + 1 H2O3- -> 2 H2O + 1 HO2 / 1.000e-06 / Chem / 1 H3O+ + 1 H2O4- -> 2 H2O + 1 OH + 1 O2 / 1.000e-06 / Chem / 1 H3O+ + 1 H3O2- -> 3 H2O / 1.000e-06 / Chem / 1 H3O+ + 1 NO-w -> 2 H2O + 1 HNO / 1.000e-06 / Chem / 1 H3O+ + 1 NO2-w -> 2 H2O + 1 HNO2 / 1.000e-06 / c / Chem / 1 OH+ + 1 H2O2- -> 1 H2O + 1 HO2 / 1.000e-06 / Chem / 1 OH+ + 1 H2O3- -> 1 H2O + 1 OH + 1 O2 / 1.000e-06 / Chem / 1 OH+ + 1 H2O4- -> 1 H2O + 1 HO2 + 1 O2 / 1.000e-06 / Chem / 1 OH+ + 1 H3O2- -> 2 H2O + 1 O / 1.000e-06 / Chem / 1 OH+ + 1 NO-w -> 1 H2O + 1 HNO2 / 1.000e-06 / Chem / 1 OH+ + 1 NO2-w -> 1 H2O + 1 HNO3 / 1.000e-06 / c / Chem / 1 O2+ + 1 H2O2- -> 1 H2O + 1 O3 / 1.000e-06 / Chem / 1 O2+ + 1 H2O3- -> 1 H2O + 2 O2 / 1.000e-06 / Chem / 1 O2+ + 1 H2O4- -> 1 H2O + 1 O3 + 1 O2 / 1.000e-06 / Chem / 1 O2+ + 1 H3O2- -> 1 H2O2 + 1 HO2 / 1.000e-06 / Chem / 1 O2+ + 1 NO-w -> 1 H2O + 1 NO3 / 1.000e-06 / Chem / 1 O2+ + 1 NO2-w -> 1 H2O + 1 NO2 + 1 O2 / 1.000e-06 / c / Chem / 1 NO+ + 1 H2O2- -> 1 H2O + 1 NO2 / 1.000e-06 / Chem / 1 NO+ + 1 H2O3- -> 1 H2O + 1 NO3 / 1.000e-06 / Chem / 1 NO+ + 1 H2O4- -> 1 H2O + 1 NO2 + 1 O2 / 1.000e-06 / Chem / 1 NO+ + 1 H3O2- -> 1 H2O + 1 HNO2 / 1.000e-06 / Chem / 1 NO+ + 1 NO-w -> 1 H2O + 2 NO / 1.000e-06 / Chem / 1 NO+ + 1 NO2-w -> 1 H2O + 1 NO2 + 1 NO / 1.000e-06 / Chem 1 O2- + 1 NO+ -> 1 O2 + 1 N + 1 O / 1.000e-07 / Chem 1 O3- + 1 O+ -> 1 O3 + 1 O / 2.000e-07 / Chem 1 O3- + 1 O2+ -> 1 O3 + 1 O2 / 2.000e-07 / Chem 1 O3- + 1 O2+ -> 2 O + 1 O3 / 1.000e-07 / Chem 1 O3- + 1 NO+ -> 1 O3 + 1 NO / 2.000e-07 / Chem 1 NO3- + 1 NO+ -> 1 NO3 + 1 N + 1 O / 1.000e-07 / Chem 1 NO3- + 1 O2+ -> 1 NO3 + 1 O + 1 O / 1.000e-07 / Chem 1 O- + 1 O2+ -> 1 O + 1 O2 / 2.000e-07 / Chem 1 O- + 1 O2+ + 1 O2 -> 1 O3 + 1 O2 / 2.000e-25 / Chem 1 O- + 1 NO+ + 1 O2 -> 1 NO2 + 1 O2 / 2.000e-25 / Chem 1 O2- + 1 O2+ -> 1 O2 + 1 O2 / 4.200e-07 / Chem 1 O2- + 1 NO+ + 1 O2 -> 2 O2 + 1 NO / 2.000e-25 / c ********************************************************************** c Electron Collisions: Boltz 1 N2 + 1 e <-> 1 N2v + 1 e / N2 N2v1 c -------------------------------------------------------------- c the V-T rates are V-scaled based on the P(1,0) transition c probability shown by Center & Caledonia (1971) Chem 1 N2v + 1 Ar <-> 1 N2 + 1 Ar / V-T 4.e-20 0.5 / c -------------------------------------------------------------- c the following all use the same V-V rate coefficient based on c the canonical P(1,0;0,1) V-V transition probability of 10^-3 c from Center & Caledonia (1971) c Chem c 2 N2v1 <-> 1 N2v2 + 1 N2 / V-V c 8.e-11 0.5 / c -------------------------------------------------------------- c CO2 chemistry Boltz 1 CO2 + 1 e <-> 1 CO2v + 1 e / CO2 CO2v Boltz 1 CO2 + 1 e -> 1 CO + 1 O- / CO2 CO+O- Chem 1 O- + 1 CO2 + 1 Ar -> 1 CO3- + 1 Ar / negative ion formation 1.5e-28 / Smirnov (M = He) Chem 1 O- + 2 CO2 -> 1 CO3- + 1 CO2 / negative ion formation 1.e-27 / Smirnov c -------------------------------------------------------------- c CO2 chemistry Chem 1 CO2 + 1 O -> 1 CO + 1 O2 / 4.285e-11 0. 26710. / NIST, 300-6000 K fit Chem 1 CO2 + 1 H -> 1 CO + 1 OH / 4.043e-10 0. 13280. / NIST, 300-3000 K fit c Chem c 1 CO2 + 1 O1D -> 1 CO + 1 O2 / c 2.e-10 / NIST Chem 1 CO2 + 1 O1D -> 1 CO2 + 1 O / 7.4e-11 0. -120. / NIST, 200-300 K Chem 1 CO2 + 1 O1S -> 1 CO2 + 1 O / 3.1e-11 0. -1320. / McGKG, 200-450 K c CO chemistry Chem 1 CO + 1 O + 1 N2 -> 1 CO2 + 1 N2 / 1.182e-33 0. 1470. / NIST, 250-4000 K fit Chem 1 CO + 1 O2 -> 1 CO2 + 1 O / 6.57e-12 0. 23940. / NIST, 300-6000 K fit Chem 1 CO + 1 O1D -> 1 CO2 / 7.3e-11 / NIST (73HEI/HUS) Chem 1 CO + 1 N -> 1 CN + 1 O / 3.83e-9 0. 35990. / NIST (86IBR), 4000-8000 K Chem 1 CO + 1 NO2 -> 1 CO2 + 1 NO / 1.374e-10 0. 16980. / NIST, 298-2000 K fit Chem 1 CO + 1 N2O -> 1 CO2 + 1 N2 / 1.38e-10 0. 20550. / NIST, 1060-2500 K fit Chem 1 CO + 1 H + 1 N2 -> 1 HCO + 1 N2 / 1.9e-33 0. 842. / NIST (84WAR), 300-2500 K Chem 1 CO + 1 OH -> 1 CO2 + 1 H / 2.175e-14 1.812 -593.9 / NIST, 200-2600 K fit Chem 1 CO + 1 HO2 -> 1 CO2 + 1 OH / 4.744e-10 0. 12230. / NIST, 300-2500 K fit c Negative Ion chemistry Chem 1 O- + 1 CO -> 1 CO2 + 1 e / 6.e-10 -0.32 / DNA (12-9); Smirnov Chem 1 H2O3- + 1 CO2 -> 1 CO4- + 1 H2O / 5.8e-10 / DNA (16-21) Chem 1 CO3- + 1 O -> 1 O2- + 1 CO2 / 8.e-11 / DNA (16-22) Chem 1 CO3- + 1 NO -> 1 NO2- + 1 CO2 / 9.e-12 / DNA (16-23) Chem 1 CO3- + 1 NO2 -> 1 NO3- + 1 CO2 / 8.e-11 / DNA (16-24) Chem 1 CO4- + 1 O -> 1 CO3- + 1 O2 / 1.5e-10 / DNA (16-25) Chem 1 CO4- + 1 O2 -> 1 O4- + 1 CO2 / 4.3e-10 0. 3000. / DNA (16-26) Chem 1 CO4- + 1 NO -> 1 NO3- + 1 CO2 / 4.8e-11 / DNA (16-27) End_List /